Synthesis and Properties of Ferrocene Conjugated Macrocycles with Illusory Topology of the Penrose Stairs  

作　　者：XU Jindong LAN Bin ZHU Lingyun XU Hui CHEN Xinyu LI Wenjuan YUAN Yaofeng YAN Jianfeng LI Yuanming 

机构地区：[1]Key Laboratory of Molecule Synthesis and Function Discovery(Fujian Province University),College of Chemistry,Fuzhou University,Fuzhou,350108,P.R.China [2]Henan Key Laboratory of Biomolecular Recognition and Sensing,College of Chemistry and Chemical Engineering,Shangqiu Normal University,Shangqiu,476000,P.R.China

出　　处：《Chemical Research in Chinese Universities》2024年第5期881-886,共6页高等学校化学研究（英文版）

基　　金：supported by the National Natural Science Foundation of China(Nos.22071025 and 22373019);the Key Research and Development and Promotion Projects in Henan Province,China(No.222102520032).

摘　　要：Polyferrocene macrocycles hold immense potential in the fields of molecular electronics and electrochemistry,primarily due to their multiple metal centers.However,developing highly efficient synthetic strategies for constructing these rings remains a significant challenge.In this study,we successfully synthesized triferrocenyl macrocycles using Pt-mediated coupling strategy and determined their configuration using single-crystal X-ray diffraction analysis,revealing a structure reminiscent of the Penrose Stair.We comprehensively investigated the macrocycle’s structure,photophysical properties,and employed density functional theory(DFT)calculations to gain further insights.Notably,this macrocycle exhibits several advantageous features,including a flexible structure,good solubility,and a highly efficient synthetic pathway.

关 键 词：Conjugated macrocycle Organometallic macrocycle Pt-template method 

分 类 号：O62[理学—有机化学]