电化学催化下成酯反应的最新研究进展  

Recent Progress in Electrochemical Synthesis of Carboxylic Esters

作　　者：陈衍安 周爱华[1] Chen Yanan;Zhou Aihua(College of Pharmacy,Jiangsu University,Zhenjiang,212013)

机构地区：[1]江苏大学药学院,镇江212013

出　　处：《化学通报》2024年第10期1190-1200,共11页Chemistry

摘　　要：酯类化合物在生活中或工业生产中十分常见,酯的合成方法丰富多彩。在众多方法中,电化学催化下合成酯的方法具有反应条件温和、反应过程易控、反应底物选择多样等优点,近年来受到越来越多的关注。本文根据近年来电化学催化下成酯反应所涉及反应化合物的类型,分别从含羧酸化合物和非羧酸化合物两方面进行了总结和介绍,旨在为电化学催化构建羧酸酯键的研究提供一定参考。Ester compounds are widely used in daily life or industrial production,and there are many ways to synthesize ester.Among these synthesis methods,synthesis of esters under electrochemical catalysis has the advantages of mild reaction conditions,easy control of reaction process and diverse selection of reaction substrates,etc.,which has attracted more and more attention in recent years.In this review,according to the types of reaction compounds involved in electrocatalytic ester formation in recent years,the literature reports on carboxylic acid compounds and non-carboxylic acid compounds are summarized and analyzed.The objective is to offer some direction for the investigation of carboxylate bond formation by electrochemical catalysis.

关 键 词：电化学 成酯反应 氧化交叉脱氢偶联 

分 类 号：O621.251[理学—有机化学]