静电纺ZnO/Fe_(2)O_(3)/CNTs复合纳米纤维光催化降解亚甲基蓝的性能研究  

Study on Photocatalytic Degradation of Methylene Blue by Electrostatic Spinning ZnO/Fe_(2)O_(3)/CNTs Composite Nanofibers

作　　者：谢仁早 陈家珺 谢冬利 谭萍红 米郅慧 张桐玮 刘晓凤 Xie Renzao;Chen Jiajun;Xie Dongli;Tan Pinghong;Mi Zhihui;Zhang Tongwei;Liu Xiaofeng(School of Chemistry and Environmental Engineering,Baise University,Baise 533000,China;School of Materials Science and Engineering,Baise University,Baise 533000,China;Laboratory of Ecological Environment Analysis and Pollution Control in the Western Guangxi Region,Baise 533000,China;Key Laboratory of Urban Water Environment,Baise 533000,China)

机构地区：[1]百色学院化学与环境工程学院,广西百色533000 [2]百色学院材料科学与工程学院,广西百色533000 [3]桂西区域生态环境分析和污染控制实验室,广西百色533000 [4]广西城市水环境重点实验室,广西百色533000

出　　处：《山东化工》2024年第18期9-11,15,共4页Shandong Chemical Industry

基　　金：2022年百色学院自治区级大学生创新创业立项项目(S202210309229);广西高校中青年教师科研基础能力提升项目(2022KY0736)。

摘　　要：采用静电纺丝技术制备ZnO/Fe_(2)O_(3)/CNTs复合纳米纤维材料,并使用场发射扫描电镜对材料形貌进行表征。探究了复合材料中两种氧化物的物质的量比、焙烧温度、染料初始浓度、光催化时间、光源等条件对复合材料光催化降解有机染料性能的影响。结果表明,ZnO/Fe_(2)O_(3)/CNTs复合纳米纤维材料在锌铁物质的量比为2∶1,亚甲基蓝初始质量浓度为15 mg/L,光照时间为3 h,光源为紫外线高压汞灯的条件下降解效果最佳,降解率达到97.07%。该实验结果可为光催化降解亚甲基蓝污水提供一定的参考价值。ZnO/Fe_(2)O_(3)/CNTs composite nanofiber materials were prepared by electrospinning,and the morphology of the materials was characterized by field emission scanning electron microscopy.The effects of molar ratio,roasting temperature,initial concentration of dye,photocatalytic time and light source of the two oxides on the photocatalytic degradation of organic dyes in the composites were investigated.The results showed that the ZnO/Fe_(2)O_(3)/CNTs composite nanofiber materials had the best degradation effect under the conditions of Zn-iron molar ratio of 2∶1,initial concentration of methylene blue of 15 mg/L,illumination time of 3 h,and ultraviolet high-pressure mercury lamp,with a degradation rate of 97.07%.The experimental results can provide a certain reference value for the photocatalytic degradation of methylene blue wastewater.

关 键 词：静电纺丝 光催化降解 亚甲基蓝 

分 类 号：TQ340.64[化学工程—化纤工业]