Pollution Characteristics and Ecological Impact of Screening Analysis of Fishing Port Sediments from Dalian,North China  

作　　者：Haichao Mu Xulin Hou Zilan Wu Jiaojiao Li Wenwen Wang Meiling Lu Xing Liu Ziwei Yao 

机构地区：[1]Key Laboratory for Ecological Environment in Coastal Areas,Ministry of Ecology and Environment,National Marine Environmental Monitoring Center,Dalian 116023,China [2]School of Light Industry and Chemical Engineering,Dalian Polytechnic University,Dalian 116034,China [3]College of Marine Science and Environment Engineering,Dalian Ocean University,Dalian 116023,China [4]Agilent Technologies(China)Ltd.,Inc.,Beijing 100102,China [5]Laboratory for Ecological Environment in Coastal Areas,Ministry of Ecology and Environment,National Marine Environmental Monitoring Center,Dalian 116023,China

出　　处：《Environment & Health》2024年第10期702-711,共10页环境与健康（英文）

基　　金：supported by the National Key Research and Development Program(2022YFC3105500);the National Natural Science Foundation of China(42206159);the Dalian Young Star of Science and Technology Project(2022RQ052).

摘　　要：Environmental pollution from synthetic chemical mixtures has significant adverse impacts on marine ecosystems.However,identifying the main constituents of chemical mixtures that pose ecological threats is challenging due to the necessity of an integrated workflow for comprehensive identification and toxicological prioritization of pollutants.Here,an all-in-one mass spectrometric strategy integrating target,suspect,and nontarget analysis was used to investigate organic pollutants of concern in fishing port sediments,with 355 pollutants(32 from target analysis,118 from suspect screening and 205 from nontarget analysis)identified in 11 categories.The chemical classes of polycyclic aromatic hydrocarbons(PAHs),pesticides,and intermediates were the extensively detected chemical classes.The ecological risks of absolutely quantified pollutants(i.e.,16 parent PAHs,7 organophosphate esters(OPEs),10 pesticides and 4 benzotriazole ultraviolet absorbers)were assessed using toxicity-weighted concentration ranking,with o,p’-DDT being the major contributor.Under the toxicological priority index(ToxPi)framework,an extended ranking of all identified pollutants was achieved by combining instrument response and detection frequency,with a priority control list of 15 pollutants obtained,of which benzo[ghi]perylene(BghiP)and p,p’-DDE had the highest risk priority.Due to frequent detection rates and significant environmental risks,routine monitoring of petroleum pollutants is considered essential.This study presents a general workflow that includes comprehensive identification and prioritization of pollutants,facilitating chemical management and ecological risk assessment.

关 键 词：fishing port sediments suspect screening nontarget analysis toxicity-weighted concentration ToxPi ecological risk assessment 

分 类 号：X52[环境科学与工程—环境工程]