Who is Who in the Carbene Chemistry of N-Sulfonyl Hydrazones  

作　　者：Paramasivam Sivaguru Yongzhen Pan Nan Wang Xihe Bi 

机构地区：[1]Departmentof Chemistry,Northeast Normal University,Changchun,Jilin130024,China

出　　处：《Chinese Journal of Chemistry》2024年第17期2071-2108,共38页中国化学（英文版）

基　　金：the financial support from the National Natural Science Foundation of China(22331004)。

摘　　要：Over the past few decades,N-sulfonyl hydrazones have been recognized as alternative precursors for hazardous diazo compounds in organic synthesis,allowing for diverse innovative and original chemical transformations that were otherwise difficult to achieve.This critical review summarizes the major advancements in the carbene chemistry of N-sulfonyl hydrazones.The contents of this review are organized based on research conducted by leading scientists who have made significant contributions to this field.The individual carbene transfer reactions and their mechanisms,as well as the potential applications in the synthesis of natural products and complex bioactive molecules,are thoroughly discussed.

关 键 词：N-Sulfonyl hydrazones Carbene chemistry Cross-coupling Cycloaddition Asymmetric reactions 

分 类 号：O62[理学—有机化学]