Self-assembled monolayers(SAMs)in inverted perovskite solar cells and their tandem photovoltaics application  

作　　者：Zijun Yi Xin Li Yuchen Xiong Guibin Shen Wenguang Zhang Yihuai Huang Qinghui Jiang Xin Ren Ng Yubo Luo Jianghui Zheng Wei Lin Leong Fan Fu Tongle Bu Junyou Yang 

机构地区：[1]State Key Laboratory of Material Processing and Die&Mould Technology,Huazhong University of Science and Technology,Wuhan,China [2]China‐Eu Institute for Clean and Renewable Energy,Huazhong University of Science and Technology,Wuhan,China [3]School of Electrical and Electronic Engineering,Nanyang Technological University,Singapore,Singapore [4]Department of Chemistry,National University of Singapore,Singapore,Singapore [5]School of Physics,The University of Sydney,Sydney,New South Wales,Australia [6]Laboratory for Thin Films and Photovoltaics,Empa‐Swiss Federal Laboratories for Materials Science and Technology,Dübendorf,Switzerland [7]State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan,China

出　　处：《Interdisciplinary Materials》2024年第2期203-244,共42页交叉学科材料（英文）

基　　金：National Key Research and Development Program of China,Grant/Award Number:2020YFA0715000;National Natural Science Foundation of China,Grant/Award Numbers:22279099,62304082,52322315;Natural Science Foundation of Hubei Province,Grant/Award Number:2023AFB087。

摘　　要：Self-assembled monolayers(SAMs)employed in inverted perovskite solar cells(PSCs)have achieved groundbreaking progress in device efficiency and stability for both single-junction and tandem configurations,owing to their distinctive and versatile ability to manipulate chemical and physical interface properties.In this regard,we present a comprehensive review of recent research advancements concerning SAMs in inverted perovskite singlejunction and tandem solar cells,where the prevailing challenges and future development prospects in the applications of SAMs are emphasized.We thoroughly examine the mechanistic roles of diverse SAMs in energy-level regulation,interface modification,defect passivation,and charge transportation.This is achieved by understanding how interfacial molecular interactions can be finely tuned to mitigate charge recombination losses in inverted PSCs.Through this comprehensive review,we aim to provide valuable insights and references for further investigation and utilization of SAMs in inverted perovskite single‐junction and tandem solar cells.

关 键 词：inverted perovskite solar cells power conversion efficiency self-assembled monolayers TANDEM 

分 类 号：TM914.4[电气工程—电力电子与电力传动]