Exfoliation and Engineering of 2D Materials Through Electrochemistry  

作　　者：Sheng Yang Panpan Zhang Ali Shaygan Nia Xinliang Feng 

机构地区：[1]Frontiers Science Center for Transformative Molecules,School of Chemistry and Chemical Engineering,Shanghai Jiao Tong University,Shanghai 201203 [2]State Key Laboratory of Material Processing and Die&Mould Technology,School of Materials Science and Engineering,Huazhong University of Science and Technology,Wuhan 430074 [3]Center for Advancing Electronics Dresden(cfaed),Faculty of Chemistry and Food Chemistry,Technische Universität Dresden,Dresden 01069 [4]Max Planck Institute for Microstructure Physics,Halle(Saale)06120

出　　处：《CCS Chemistry》2024年第10期2368-2391,共24页中国化学会会刊（英文）

基　　金：the National Natural Science Foundation of China(grant nos.22205141 and 22209051);the Shanghai Pujiang Program,China(grant no.22PJ1408300);the Fundamental Research Funds for the Central Universities of China(grant no.23X010301599);European Research Council(ERC)Consolidator Grant on T2DCP,M-ERANET project HYSUCAP,SPES3 project funded by German Ministry for Education and Research(BMBF)under Forschung für neue Mikroelektronik(ForMikro)program.

摘　　要：Two-dimensional(2D)materials offer countless possibilities for next-generation(opto)electronic devices because of their diverse and tailorable physicochemical characteristics.To bridge the gap between fundamental science and practical applications,simple-to-use universal approaches are essential for the mass production of 2D materials with specific target properties.Electrochemical intercalation/exfoliation stands out from many up-scalable synthetic strategies,thanks to its great time efficiency,mild working conditions,and simple instrumentation.Besides the use for direct exfoliation of 2D materials,device-level controllable intercalation of guest species often results in rich phase diagrams with competing orders and ground states in 2D systems,giving rise to new exotic quantum phenomena.Therefore,making use of electrochemistry in ion intercalation and host–guest interaction is crucial to expand the library,as well as the function of 2D materials.Here,we present a focused review of the exciting advances of electrochemical exfoliation and engineering of 2D materials,including intercalation strategies,intercalation chemistry,exfoliation mechanisms,material properties,and potential applications.An outlook on the major challenges and perspectives is also presented at the end of the discussion.

关 键 词：INTERCALATION EXFOLIATION 2D materials ELECTROCHEMISTRY 

分 类 号：O646[理学—物理化学]