What Can Topology Bring to Chemistry?  

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作  者:Wei Wang Songtao Zhou Xiujun Yu Qing-Hui Guo Yanhang Ma Jie Song Liang Zhang Xuzhou Yan Lu Han Qing Liao Xiaopeng Li Wen-Bin Zhang Yiyong Mai Shaodong Zhang Shunai Che Hai-Bo Yang Xuefeng Fu Mei-Xiang Wang 

机构地区:[1]School of Chemistry and Molecular Engineering,East China Normal University,Shanghai 200062 [2]Hangzhou Institute of Medicine,Chinese Academy of Sciences,Hangzhou 310022,Zhejiang [3]College of Chemistry and Environmental Engineering,Shenzhen University,Shenzhen 518060,Guangdong [4]MOE Key Laboratory of Bioorganic Phosphorous and Chemical Biology,Department of Chemistry,Tsinghua University,Beijing 100084 [5]School of Physical Science and Technology and Shanghai Key Laboratory of High-Resolution Electron Microscopy,ShanghaiTech University,Shanghai 201210 [6]School of Chemistry and Chemical Engineering,Frontiers Science Center for Transformative Molecules,State Key Laboratory of Composite Materials,Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs,Shanghai Jiao Tong University,Shanghai 200240 [7]School of Chemical Science and Engineering,Tongji University,Shanghai 200092 [8]Beijing Key Laboratory for Optical Materials and Photonic Devices,Department of Chemistry,Capital Normal University,Beijing 100048 [9]Beijing National Laboratory for Molecular Sciences,Key Laboratory of Polymer Chemistry and Physics of Ministry of Education,Center for Soft Matter Science and Engineering,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871 [10]Department of Chemical Sciences,National Natural Science Foundation of China,Beijing 10085

出  处:《CCS Chemistry》2024年第9期2084-2109,共26页中国化学会会刊(英文)

基  金:financially supported by the science and technology activity program of the National Natural Science Foundation of China(grant no.22242005)。

摘  要:The unique mathematical perspectives and principal concepts of topology have not only promoted the development of other branches of mathematics but have also deeply influenced other subjects,particularly physics and chemistry.This minireview aims to elucidate the substantial influence of topology on chemistry by critically examining both the contributions of topology to current chemical science and its potential future impacts.We will discuss the topology of molecular structures and assemblies across various scales—from small molecules and mechanically interlocked molecules to polymers,biomacromolecules,and supramolecular networks.This discussion will include an exploration of cutting-edge techniques for characterizing topological features,underscoring the role of topology as a novel paradigm for the design and synthesis of new molecular assemblies.Furthermore,a critical analysis of topology’s role in the development of functional materials—such as photonic materials,polymers,biomacromolecules,and chiral materials—will demonstrate its emerging significance as a crucial parameter in unveiling novel properties and functionalities.Given topology’s formidable potential,it is anticipated to be used increasingly to address pivotal challenges within chemistry and adjacent disciplines.

关 键 词:chemical topology topological invariants molecular graphs links and knots structureproperty relationship 

分 类 号:O62[理学—有机化学]

 

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