The effect of the carbon components on the performance of carbonbased transition metal electrocatalysts for the hydrogen evolution reaction  

碳组分对碳基过渡金属电解水析氢催化剂性能影响

作　　者：LI Guo-hua WANG Jing REN Jin-tian LIU Hong-chen QIAN Jin-xiu CHENG Jia-ting ZHAO Mei-tong YANG Fan LI Yong-feng 李国华;王静;任锦添;刘洪辰;钱锦绣;程佳婷;赵美彤;杨帆;李永峰(中国石油大学(北京)重油加工国家重点实验室,北京102249)

机构地区：[1]State Key Laboratory of Heavy Oil Processing,China University of Petroleum(Beijing),Beijing 102249,China

出　　处：《新型炭材料（中英文）》2024年第5期946-972,共27页New Carbon Materials

基　　金：国家自然科学基金(No.22278431、No.21776302).

摘　　要：The hydrogen evolution reaction(HER)is a promising way to produce hydrogen,and the use of non-precious metals with an excellent electrochemical performance is vital for this.Carbon-based transition metal catalysts have high activity and stability,which are important in reducing the cost of hydrogen production and promoting the development of the hydrogen production industry.However,there is a lack of discussion regarding the effect of carbon components on the performance of these electrocatalysts.This review of the literature discusses the choice of the carbon components in these catalysts and their impact on catalytic performance,including electronic structure control by heteroatom doping,morphology adjustment,and the influence of self-supporting materials.It not only analyzes the progress in HER,but also provides guidance for synthesizing high-performance carbon-based transition metal catalysts.析氢反应,作为一种最有前途的制氢技术其在能源转换和存储领域的重要性日益凸显。开发具有优异电化学性能的非贵金属材料对促进电催化的实际应用至关重要。碳基过渡金属催化剂具有较高的活性和稳定性,对降低氢气生产成本和促进氢气工业的发展具有重要意义。然而目前仍缺乏关于碳组分对碳基过渡金属电催化剂性能影响的相关综述。因此,本文总结了与电解水析氢有关的过渡金属/碳的文献,讨论了复合结构中碳组分的设计策略及其对催化性能的影响,包括杂原子掺杂的电子结构调整、形貌调整、以及自支撑材料对碳基过渡金属催化剂的影响。这篇综述不仅分析了电解水析氢反应的进展,而且为指导高性能碳基过渡金属催化剂的合成提供了见解。

关 键 词：Carbon-based transition metal catalysts Heteroatom doping Morphology adjustment Self-supporting materials Hydrogen evolution reaction 

分 类 号：TQ127.11[化学工程—无机化工]