腰果酚阳离子表面活性剂的合成及其表面性能  

Synthesis and Surface Properties Study of Cardanol Cationic Surfactants

作　　者：张元炜 莫立鑫 詹强 涂柯鑫 刘展鹏 李建滨 吕晓奇 钱俊红[1] Zhang Yuanwei;Mo Lixin;Zhan Qiang;Tu Kexin;Liu Zhanpeng;Li Jianbin;Lv Xiaoqi;Qian Junhong(Shanghai Key Laboratory of Functional Materials Chemistry,School of Chemistry and Molecular Engineering,East China University of Science and Technology,Shanghai 200237,China;Anhui Meidong Biomedical Materials Corporation,Chuzhou 239500,China)

机构地区：[1]华东理工大学化学与分子工程学院上海市功能材料重点实验室,上海200237 [2]安徽美东生物材料有限公司,安徽滁州239500

出　　处：《广东化工》2024年第19期63-65,68,共4页Guangdong Chemical Industry

基　　金：安徽省重点研究与开发计划(2022i01020028)。

摘　　要：以腰果酚缩水甘油醚(CGE)为原料,通过两条季铵化路线合成得到了四个腰果酚基季铵盐表面活性剂,采用单因素实验法对两条路线进行工艺优化,通过核磁、IR与ESI-Mass鉴定了化合物结构;测定了表面活性剂溶液的表面张力γ、乳化性能、泡沫性能等表面性能。结果表明:合成的四种季铵盐阳离子化合物具有良好的表面活性,与市售表面活性剂十二烷基苯磺酸钠(SDBS)相比,其具有更低的CMC值、更好的乳化性能、增溶性能和较低的起泡高度。Four cashew phenol-based quaternary ammonium salt surfactants were synthesized through two quaternization routes with cardanol glyceryl ether(CGE)as the raw material.The process conditions of both routes was were optimized by single-factor experimental method.The compound structures were identified by NMR,IR and ESI-Mass.The surface tensionγ,emulsification performance,foamability,and other surface properties of the surfactant solutions were determined.The results showed that the synthesized quaternary ammonium salt cationic compounds exhibited good surface activities.Compared with the commercial surfactant SDBS,the synthesized surfactants had lower critical micelle concentration(CMC),better emulsification performance and solubilization capacity,and lower foam height.

关 键 词：腰果酚 表面性能 季铵盐表面活性剂 工艺优化 

分 类 号：TQ[化学工程]