氟硅聚合物海洋防污涂料研究进展  

Research progress in marine antifouling coatings based on fluorosilicone

作　　者：李曦 王鑫 齐文 戚丁文 LI Xi;WANG Xin;QI Wen;QI Dingwen(School of Chemistry and Chemical Engineering,Guangxi Minzu University,Key Laboratory ofChemistry and Engineering of Forest Products,State Ethnic Affairs Commission,Guangxi Key Laboratory ofChemistry and Engineering of Forest Products,Guangxi Collaborative Innovation Center for Chemistry andEngineering of Forest Products,Guangxi Minzu University,Nanning 530006,China;Liaoning Inspection,Examination&Certification Centre,Shenyang 110032,China)

机构地区：[1]广西民族大学化学化工学院,林产化学与工程国家民委重点实验室,广西林产化学与工程重点实验室/协同创新中心,南宁530006 [2]辽宁省检验检测认证中心,沈阳110032

出　　处：《中国塑料》2024年第10期55-59,共5页China Plastics

基　　金：广西高等学校千名中青年骨干教师培育计划;广西科技基地和人才专项(桂科AD20297016);广西民族大学2019年引进人才科研启动项目(2019KJQD11);辽宁省自然科学基金指导计划(2019-ZD-0848)。

摘　　要：海洋生物污损严重制约了海洋资源的开发利用,涂装海洋防污涂料是目前避免海洋生物污损最广泛、最有效、最经济的手段之一。氟硅聚合物海洋防污涂料是一类非常具有发展前景的污损脱附型涂料,本文介绍了氟硅聚合物的4种常见的合成方法,包含阴离子开环聚合法、原子转移自由基聚合法(ATRP)、硅氢加成反应法、硫醇⁃烯点击法,同时从有机链段改性和纳米材料改性两方面介绍了氟硅聚合物的改性研究进展,并指出了氟硅聚合物海洋防污涂料面临的挑战和未来发展方向。The severe pollution of marine organisms has greatly restricted the development and utilization of marine resources.At present the surface coating with marine anti⁃fouling coatings is one of the most widely used,effective,and economical methods to avoid marine organism pollution.The marine anti⁃fouling coatings based on fluorosilicone polymers are a class of non⁃stick coatings with great development prospects.This article introduced four common methods for synthesizing fluorosilicone polymers,including anionic ring⁃opening polymerization,atom transfer radical polymerization,hydrosilylation reaction,and thiol⁃ene click reaction.The research progress in the modification of fluorosilicone polymers was reviewed from the perspectives of organic chain segment modification and nanomaterial modification.Furthermore,the challenges and future development directions for the marine anti⁃fouling coatings based on fluorosilicone polymers were proposed.

关 键 词：氟硅聚合物 海洋防污涂料 聚氨酯 环氧树脂 丙烯酸系列化学品 纳米材料 

分 类 号：TQ325[化学工程—合成树脂塑料工业]