天然酚基动态共价键高分子材料研究进展  

Research Progress in Natural Phenol-based Dynamic Covalent Polymer Materials

作　　者：周航 李沿霖 谭艺 刘承果 ZHOU Hang;LI Yanlin;TAN Yi;LIU Chengguo(College of Chemical Engineering,Nanjing Forestry University,Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources,Jiangsu Key Lab of Biomass-based Green Fuel and the Chemicals,Nanjing 210037,China;School of Materials Science and Technology,Beijing Forestry University,Key Laboratory of Wooden Material Science and Application of Ministry of Education,Beijing Key Laboratory of Wood Science and Engineering,Beijing 100083,China)

机构地区：[1]南京林业大学化学工程学院,江苏省林业资源高效加工利用协同创新中心,江苏省生物质绿色燃料与化学品重点实验室,江苏南京210037 [2]北京林业大学材料科学与技术学院,木质材料科学与应用教育部重点实验室,木材科学与工程北京市重点实验室,北京100083

出　　处：《林产化学与工业》2024年第5期185-198,共14页Chemistry and Industry of Forest Products

基　　金：南京林业大学水杉学者启动资金(无编号)。

摘　　要：综述了近年来关于天然酚基动态共价键高分子材料的研究进展,其内容主要包括2方面:首先总结了天然酚资源的基本概况以及动态共价键的发展和特点,着重强调了动态共价键往往同时具有重排和分解2种机理;其次归纳了天然酚基高分子材料的研究进展,其中涉及的动态共价键种类包括席夫碱、二硫键、羟基-酯键、缩醛键和硼酸酯键,涉及的天然酚基原料主要包括香草醛、丁香酚、阿魏酸、漆酚、腰果酚、柚皮素、愈创木酚、单宁酸等,旨在推动塑料污染治理及绿色材料的研究和应用。The research progress of natural phenol-based dynamic covalent polymer materials in recent years was reviewed,which mainly included two aspects.Firstly,the basic situation of natural phenolic resources,the development history and characteristics of dynamic covalent bonds were summarized,emphasizing that the dynamic covalent bonds often had two mechanisms of rearrangement and disassociation at the same time.Secondly,the research progress of natural phenol-based polymer materials was reviewed.The involved types included Schiff base,disulfide bond,hydroxy-ester bond,acetal bond,and borate bond.The referred natural phenol-based raw materials mainly included vanillin,eugenol,ferulic acid,urushiol,cashew phenol,naringin,guaiacol,tannic acid,etc.The purpose of this review was to promote the plastic pollution control as well as the research and application of green materials.

关 键 词：天然酚 动态共价键聚合物 自修复 可回收加工 

分 类 号：TQ35[化学工程] TQ317