可见光催化不对称Minisci反应研究进展  

Developments in Visible Light Catalyzed Asymmetric Minisci Reactions

作　　者：李文雅 王煜 陈江琦 史丹 张良 余小春[1] 王正军 Li Wenya;Wang Yu;Chen Jiangqi;Shi Dan;Zhang Liang;Yu Xiaochun;Wang Zheng-Jun(College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou,Zhejiang 325035;Wenzhou Market Supervision Administration,Wenzhou Quality and Technical Testing Science Research Institute,Wenzhou,Zhejiang 325052;State Key Laboratory of Chemo/Biosensing and Chemometrics,Hunan University,Changsha 410082)

机构地区：[1]温州大学化学与材料工程学院,浙江温州325035 [2]温州市市场监督管理局、温州市质量技术检测科学研究院,浙江温州325052 [3]湖南大学化学生物传感与计量学国家重点实验室,长沙430100

出　　处：《有机化学》2024年第7期2110-2123,共14页Chinese Journal of Organic Chemistry

基　　金：湖南大学化学生物传感与计量学国家重点实验室开放项目(No.20230767);温州市基础性科研(No.G20220020)资助项目。

摘　　要：氮杂芳烃是诸多天然产物、药物和有机材料中常见的结构单元之一,因此以Minisci反应为代表的对氮杂芳烃进行选择性官能团化修饰一直以来是化学家们的关注热点.同时,近年来光催化作为一种绿色安全、洁净环保和可再生的催化方式掀起了新的研究热潮.尽管近年来光催化Minisci反应已经有相关综述报道,但是对于不对称Minisci反应却一直鲜有涉猎.将从自由基前驱体的分类、不同的反应途径等方面概述近年来可见光催化不对称Minisci反应的研究进展,同时也对今后其发展方向进行了展望.N-Heterocyclic aromatics are among the most prevalent motifs in natural products,pharmaceuticals,and organic materials.Therefore,the selective functionalization of N-heterocyclic aromatics,represented by the Minisci reaction,has al-ways been a hot topic for chemists.Meanwhile,in recent years,photocatalysis has sparked a new research trend as a green,safe,clean,and renewable catalytic method.Although a review has been conducted on photoinduced Minisci reactions in re-cent years,the exploration of asymmetric Minisci reactions is limited.The research progress on visible-light photocatalytic asymmetric Minisci reactions in recent years from the classification of free radical precursors and different reaction pathways is summarized.Furthermore,prospects for future development are also discussed.

关 键 词：不对称Minisci反应 光催化 含氮芳环 自由基 

分 类 号：O643.36[理学—物理化学] O644.1[理学—化学]