乙烯基共价有机框架材料研究进展  

Progress in vinylene-linked covalent organic frameworks

作　　者：李月明 申雅靓 刘明杰[1,2] 林月敏 鲍宗必 杨启炜[1,2] 张治国 LI Yueming;SHEN Yajing;LIU Mingjie;LIN Yuemin;BAO Zongbi;YANG Qiwei;ZHANG Zhiguo(Key Laboratory of Biomass Chemical Engineering of Ministry of Education,College of Chemical and Biological Engineering,Zhejiang University,Hangzhou 310058,China;Institute of Zhejiang University-Quzhou,Quzhou 324000,China)

机构地区：[1]浙江大学生物质化工教育部重点实验室,浙江大学化学工程与生物工程学院,浙江杭州310058 [2]浙江大学衢州研究院,浙江衢州324000

出　　处：《高校化学工程学报》2024年第5期681-702,共22页Journal of Chemical Engineering of Chinese Universities

基　　金：国家自然科学青年基金(22208294,22201248,22271248)。

摘　　要：共价有机框架(COFs)是一类基于共价键连接的多孔晶态有机聚合物,因其结构的多样性和丰富的功能化位点使得其在诸多领域展现出良好的应用潜力。然而基于可逆共价键设计的COFs材料有限的化学稳定性限制了此类材料的进一步应用。近年来,由于化学稳定性的提升,基于C=C双键构筑得到的乙烯基COFs(V-COFs)逐渐成为研究热点。本综述旨在通过系统总结此类新兴V-COFs材料的合成方法和应用情况,深入分析其研究进展,对V-COFs材料的未来发展提出展望。Covalent organic frameworks(COFs)are a class of porous crystalline organic polymers based on covalent bonds,which show excellent potential in many applications due to their structural diversity and rich functionalization sites.However,the insufficient chemical stability of reversible-covalent-bond-based COFs limits their usage in different fields.Vinylene-linked COFs(V-COFs)with the construction of C=C double bonds become highly focused due to their improved chemical stability.This review aims at summarizing the preparation methods and corresponding applications of V-COFs,analyzing the progress of V-COFs,and further prospecting the future development of V-COFs.

关 键 词：乙烯基共价有机框架材料 合成策略 光催化 有机发光材料 吸附 

分 类 号：TB32[一般工业技术—材料科学与工程]