Recent advances in phenazine-linked porous catalysts toward photo/electrocatalytic applications and mechanism  

作　　者：Yang Liu Yu Zhang Zhao-Di Yang Liqiang Jing 

机构地区：[1]Heilongjiang Provincial Key Laboratory of CO_(2) Resource Utilization and Energy Catalytic Materials,School of Material Science and Chemical Engineering,Harbin University of Science and Technology,Harbin,Heilongjiang,150080,China [2]Institute of Process Engineering,Chinese Academy of Sciences,100080,Beijing,China [3]Key Laboratory of Functional Inorganic Materials Chemistry(Ministry of Education),School of Chemistry and Materials Science,International Joint Research Center for Catalytic Technology,Heilongjiang University,Harbin,150080,China

出　　处：《Green Energy & Environment》2024年第10期1518-1549,共32页绿色能源与环境（英文版）

基　　金：supported by the Natural Science Foundation of China(52273288 and U2102211);the Natural Science Foundation of Heilongjiang Province of China(LH2021B014);the Fundamental Research Foundation for Universities of Heilongjiang Province(2021-KYYWF-0004).

摘　　要：In recent years,porous organic catalysts have been developed and become research hotspots in photo/electrocatalysis due to their inherent pores,high specific surface area,chemical and thermal stability,and diverse functional building blocks.Phenazine-linked organic catalysts,exhibited excellent conjugation,electrical conductivity,chemical,and thermal stability,could bring in N atoms with specific numbers and positions to regulate electron levels,anchor metals,and absorb near-infrared light,which expands solar energy utilization.These advantages of the phenazine-linked catalysts attracted our group and numerous researchers to conduct experimental and computational work on photo/electrocatalytic applications and mechanisms.This review summarizes the recent significant research progress,synthesis methods,photo/electrocatalytic performance,and applications of relative phenazine-linked catalysts.Furthermore,the photo/electrocatalytic mechanism was systematized and summarized by combining experiments and density functional theory calculations simultaneously.

关 键 词：Phenazine-linked porous catalysts Photo/electrocatalytic applications Catalytic mechanism 

分 类 号：O643.36[理学—物理化学]