MOF synthesis using waste PET for applications of adsorption, catalysis and energy storage  

作　　者：Hongmei Li Jinming Lei Liying Zhu Yanling Yao Yuanhua Li Tianhao Li Chuntian Qiu 

机构地区：[1]College of Food and Bioengineering,Chengdu University,Chengdu,610106,China [2]ZJU-Hangzhou Global Scientifc and Technological Innovation Center,Zhejiang University,Hangzhou,311215,China [3]School of Chemistry and Materials Engineering,Huizhou University,Huizhou,516007,China [4]Chongqing Key Laboratory for Advanced Materials and Technologies of Clean Energy,School for Materials and Energy,Southwest University,Chongqing,400715,China [5]Yibin Academy of Southwest University,University Road,Yibin,Sichuan,644005,China

出　　处：《Green Energy & Environment》2024年第11期1650-1665,共16页绿色能源与环境（英文版）

基　　金：supported by the National Natural Science Foundation of China(21902105,52274172);Shenzhen Science and Technology Program(JCYJ20210324094000001);Guangdong Basic and Applied Basic Research Foundation(2020A1515010471).

摘　　要：Polyethylene terephthalate (PET) as one of non-degradable wastes has become a huge threat to the environment and human health.Chemical Recycle of PET is a sustainable way to release 1,4-benzenedicarboxylic acid (BDC) the monomer of PET as common used organiclinker for synthesis of functional Metal–organic-frameworks (PET-derived MOFs) such as UiO-66, MIL-101, etc. This sustainable and costeffective“Waste-to-MOFs” model is of great significant to be intensively investigated in the past years. Attributes of substantial porosity, specificsurface area, exposed metal centers, uniform structure, and flexible morphology render PET-derived MOFs are well-suited for applications inadsorption, energy storage, catalysis, among others. Herein, in the present work, we have summarized recent advances in synthesis of PETderived MOFs using ex-situ and in-situ methods for typical applications of adsorption, catalysis and energy storage. Despite those improvementsin synthesis methods and potential applications, challenges still remain in development of green and economical routes to fully utilize waste PETfor massive manufacture of valuable MOF materials and chemicals. This review provides insights into the conversion of non-degradable PETwaste to value-added MOF materials, and further suggests promising perspectives to develop the sustainable “Waste-to-MOFs” model inaddressing environmental pollution and energy crises.

关 键 词：Plastic waste Polyethylene terephthalate Chemical recycle 1 4-benzenedicarboxylic acid Metal organic frameworks 

分 类 号：X705[环境科学与工程—环境工程]