多组分锆基金属有机骨架研究进展  

Recent progress in multicomponent zirconium‑based metal‑organic frameworks

作　　者：何斌 张浩 徐琳 刘阳河 郎飞帆 庞建东 HE Bin;ZHANG Hao;XU Lin;LIU Yanghe;LANG Feifan;PANG Jiandong(School of Materials Science and Engineering,Nankai University,Tianjin 300350,China)

机构地区：[1]南开大学材料科学与工程学院,天津300350

出　　处：《无机化学学报》2024年第11期2041-2062,共22页Chinese Journal of Inorganic Chemistry

基　　金：国家重点研发计划(No.2022YFA1502901);国家自然科学基金(No.22371137,22201137);中央高校基本科研业务费(No.63243115)资助。

摘　　要：锆基金属有机骨架(Zr-MOFs)具有丰富的结构类型、出色的热稳定性和化学稳定性以及多样化的功能,被认为是最具应用前景的新型晶态多孔骨架材料之一。通过一锅法及合成后修饰法等多种方法可将具有特定功能化官能团的有机配体引入Zr-MOFs体系,进而实现多组分锆基金属有机骨架(MC-Zr-MOFs)的构筑及对Zr-MOFs孔道环境的有效调控。MC-Zr-MOFs被广泛应用于气体吸附与分离、溶液相客体分子/离子吸附、多相催化、化学传感及光学材料等领域,展现出优异的性能。本文详细梳理了MC-Zr-MOFs的合成策略和应用研究的近期进展,并对其未来发展前景进行了展望。Zirconium-based metal-organic frameworks(Zr-MOFs)have emerged as one of the most promising crys-talline porous framework materials for various applications,owing to their abundant structural varieties,excellent thermal and chemical stability as well as diverse functionalities.Incorporating organic ligands with tailored function-al groups into the Zr-MOFs system via various methods such as one-pot synthesis and post-synthetic modification enables the construction of multicomponent zirconium-based metal-organic frameworks(MC-Zr-MOFs),allowing precise regulation over their pore environment for particular requirements.MC-Zr-MOFs have found extensive utili-ty in gas adsorption/separation,guest molecule/ion adsorption in the solution phase,multiphase catalysis,chemical sensing,and optical materials for instance while exhibiting remarkable performance.This review aims to carefully investigate the recent advances in the synthetic strategies and novel applications of MC-Zr-MOFs,along with pros-pects for their future development.

关 键 词：锆基金属有机骨架 结构设计 多组分组装 孔道环境调控 结构-性能关系 

分 类 号：O614.412[理学—无机化学]