基于发光铜纳米团簇的多组分体系的构成及应用  

Construction and application of multi‑component systems based on luminous copper nanoclusters

作　　者：黄燕婷 向华 潘梅 HUANG Yanting;XIANG Hua;PAN Mei(School of Chemistry,IGCME,Sun Yat-Sen University,Guangzhou 510006,China;Guangdong Province Engineering Research Center of Anti-counterfeiting Materials and Design for Packaging and Printing,Guangdong Industry Polytechnic University,Guangzhou 510300,China)

机构地区：[1]中山大学化学学院,绿色化学与分子工程研究院,广州510006 [2]广东轻工职业技术大学,广东省包印防伪材料与设计工程技术开发中心,广州510300

出　　处：《无机化学学报》2024年第11期2075-2090,共16页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.22171291,92261114,21821003);广东省高等职业院校珠江学者岗位计划资助项目(2019)资助。

摘　　要：铜纳米团簇(copper nanoclusters,Cu NCs)具有独特而优异的光物理性质,近年来在发光领域取得了令人瞩目的研究进展。然而,由于铜易氧化,因而难以获得结构稳定、发光强度高的Cu NCs。将Cu NCs与其他组分结合构建多组分体系,是提高稳定性、优化发光性能的可行策略之一。基于Cu NCs构筑的多组分体系,不仅能够有效弥补其缺陷和不足,而且还能实现发光体系的功能多样化,从而有助于促进该发光材料的实际应用。基于此,本文对该领域的研究进行了综述,首先介绍了Cu NCs的基本结构和发光影响因素,进而分类总结了目前发光Cu NCs多组分体系的构成策略及其应用。Copper nanoclusters(Cu NCs)have made remarkable progress in the field of luminescence due to their excellent photophysical properties.However,due to the easy oxidation of copper,it is difficult to obtain Cu NCs with stable structure and high-intensity luminescence.It is one of the most feasible strategies to combine Cu NCs with other components to construct multi-component systems to improve stability and luminescence performance.Such systems can not only effectively make up for the defects of Cu NCs,but also realize the functional diversification of the luminous properties,which is conducive to the practical application of luminous materials.Based on this,this review will give a brief survey of the current study in this field,with first an introduction to the basic structure and effects on the luminescence of Cu NCs,and then a summary of the current strategies and applications of luminous multi-component systems constructed from Cu NCs.

关 键 词：铜纳米团簇 多组分 光致发光 

分 类 号：O614.121[理学—无机化学]