多孔氢键有机框架材料应用于传感和光学材料领域的研究  

Research on the application of porous hydrogen bonded organic framework materials in the fields of sensing and optical materials

作　　者：阮春晓[1] 郑庆呈 RUAN Chun-xiao;ZHENG Qing-cheng(Fujian Shipbuilding and Transportation Vocational College,Fuzhou 350007,China;Fujian Institute of Metrology,Fuzhou 350003,China)

机构地区：[1]福建船政交通职业学院,福建福州350007 [2]福建省计量科学研究院,福建福州350003

出　　处：《聚酯工业》2024年第6期86-88,共3页Polyester Industry

基　　金：2020年福建省中青年教师教育科研项目(科技类)(JAT201071);福建船政交通职业学院校科教发展基金“福建省特色农产品有效成分的提取及资源化利用”(20220204)。

摘　　要：氢键有机框架(HOFs)是一类通过有机连接基团间的氢键自组装形成的聚合物多孔材料。为实现HOF的永久多孔性,需构建稳定且坚固的开放框架,这可以通过精心设计刚性分子结构单元和强相互作用的氢键单元来达成。氢键的柔性和可逆性赋予了HOF溶液加工性、高结晶度、易于纯化和再生等特性。这些独特的优势使HOF成为研究多孔功能材料的重要平台。近年来,HOF作为多孔功能材料已在气体存储与分离、化学传感、催化、分子识别、生物医学、光学和电学材料等多个关键领域得到广泛应用。Hydrogen bonded organic frameworks(HOFs)are a type of polymer porous material formed by self-assem-bly of hydrogen bonds between organic linking groups.To achieve permanent porosity of HOF,a stable and robust open framework needs to be constructed,which can be achieved through carefully designed rigid molecular structural units and strongly interacting hydrogen bonding units.The flexibility and reversibility of hydrogen bonds endow HOF solutions with characteristics such as processability,high crystallinity,ease of purification,and regeneration.These unique advantages make HOF an important platform for studying porous functional materials.In recent years,HOF has been widely used as a porous functional material in various key fields such as gas storage and separation,chemi-cal sensing,catalysis,molecular recognition,biomedical,optical,and electrical materials.

关 键 词：氢键有机框架 HOF 传感 光学材料 

分 类 号：O658[理学—分析化学]