Nickel(Ⅱ)-Catalyzed Reductive Coupling of Xanthate Esters with Sulfur-Containing and Selenium-Containing Compounds:Synthesis of Unsymmetric Sulfides and Selenides  

作　　者：Jia-Hui Han Daopeng Sheng Yi-Rong Chen Xiao-Yue Shuai Weidong Rao Shu-Su Shen Shun-Yi Wang 

机构地区：[1]Key Laboratory of Organic Synthesis of Jiangsu Province,College of Chemistry,Chemical Engineering and Materials Science&Collaborative Innovation Centerof Suzhou Nano Science and Technology,Soochow University,Suzhou,Jiangsu 215123,China [2]Key Laboratory of Biomass-based Green Fuels and Chemicals,College of Chemical Engineering,Nanjing Forestry University,Nanjing,Jiangsu 210037,China [3]School of Environmental Science and Engineering,Suzhou University of Science and Technology,No.99,Xuefu Road,Huqiu District,Suzhou,Jiangsu 215009,China [4]State Key Laboratory of Radiation Medicine and Protection,School for Radiological and Interdisciplinary Sciences(RAD-X)and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions,Soochow University,Suzhou,Jiangsu 215123,China

出　　处：《Chinese Journal of Chemistry》2024年第20期2453-2458,共6页中国化学（英文版）

基　　金：National Natural Science Foundation of China(Nos.21971174 and U2267224),PAPD,Cyrus Tang(Zhongying)Scholar,Jiangsu Qing-Lan Project for Young and Middle-aged Academic Leaders(2023)and Soochow University for financialsupport.

摘　　要：Unsymmetric sulfides and selenides have great applications in the pharmaceutical field.Herein,we describe the reductive coupling reaction of xanthate esters with sulfur-containing and selenium-containing compounds(thio(seleno)sulfonates and disulfides(selenides))under the nickel-catalyzed condition.It provides a mild and effective method for the synthesis of unsymmetric sulfides and selenides which has the advantages of mild reaction conditions,high yields and a wide range of substrates.

关 键 词：Sulfur-containing and selenium-containing compounds Sulfides and selenides Xanthate esters Nickel Radical Synthetic methods 

分 类 号：O62[理学—有机化学]