六氟环氧丙烷阴离子开环聚合反应研究进展  

Research Progress in Anionic Ring-opening Polymerization of Hexafluoropropylene Oxide

作　　者：张文 刘波[1] 张鸣[1] 杨旭仓 钟志刚 ZHANG Wen;LIU Bo;ZHANG Ming;YANG Xucang;ZHONG Zhigang(Zhonghao Chenguang Research Institute of Chemical Industry Co.,Ltd.,Organic Fluorine Materials Sichuan Provincial Key Laboratory,Zigong 643201,China)

机构地区：[1]中昊晨光化工研究院有限公司有机氟材料四川省重点实验室,四川富顺643201

出　　处：《有机氟工业》2024年第3期34-39,共6页Organo-Fluorine Industry

摘　　要：介绍了六氟环氧丙烷在阴离子催化下的开环聚合反应研究进展,包括聚合反应条件、引发体系、工艺和反应器结构对聚合物特性的影响,并对端基处理后的聚合物在特性单体、乳化剂、润滑剂和材料改性等方面的应用现状和前景进行了分析。The research progress of ring-opening polymerization of hexafluoropropylene oxide catalyzed by anions was introduced,including the effects of polymerization conditions,initiator system,process and reactor structure on polymer properties.The application status and prospects of polymers with end-group treatment in characteristic monomers,emulsifiers,lubricants and material modification were analyzed.

关 键 词：六氟环氧丙烷 阴离子开环 端基处理 K型全氟聚醚 

分 类 号：TQ316.3[化学工程—高聚物工业]