Design of dual-functional protic porous ionic liquids for boosting selective extractive desulfurization  

作　　者：Jin-Rui Zhang Jie Yin Jing He Hong-Shun Ran Wei Jiang Hong-Ping Li Wen-Shuai Zhu Hua-Ming Li Ming Zhang 

机构地区：[1]School of the Environment and Safety Engineering&Institute for Energy Research,Jiangsu University,Zhenjiang,212013,Jiangsu,China [2]School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang,212013,Jiangsu,China

出　　处：《Petroleum Science》2024年第4期2817-2829,共13页石油科学（英文版）

基　　金：financially supported by the National Natural Science Foundation of China (Nos.22078135,21808092,21978119,22202088)。

摘　　要：Porous ionic liquids have demonstrated excellent performance in the field of separation,attributed to their high specific surface area and efficient mass transfer.Herein,task-specific protic porous ionic liquids(PPILs)were prepared by employing a novel one-step coupling neutralization reaction strategy for extractive desulfurization.The single-extraction efficiency of PPILs reached 75.0%for dibenzothiophene.Moreover,adding aromatic hydrocarbon interferents resulted in a slight decrease in the extraction efficiency of PPILs(from 45.2%to 37.3%,37.9%,and 33.5%),indicating the excellent extraction selectivity of PPILs.The experimental measurements and density functional theory calculations reveal that the surface channels of porous structures can selectively capture dibenzothiophene by the stronger electrophilicity(Eint(HS surface channel/DBT)=-39.8 kcal mol^(-1)),and the multiple extraction sites of ion pairs can effectively enrich and transport dibenzothiophene from the oil phase into PPILs throughπ...π,C-H...πand hydrogen bonds interactions.Furthermore,this straightforward synthetic strategy can be employed in preparing porous liquids,offering new possibilities for synthesizing PPILs with tailored functionalities.

关 键 词：Protic porous ionic liquids Extractive desulfurization SELECTIVITY Density functional theory 

分 类 号：TE624.55[石油与天然气工程—油气加工工程]