Corrosion Behavior of High-Chromium Alloys in Molten LiCl-KCl Eutectic  

作　　者：Mengmeng Ji Xin Li Zihe Liu Xiaoguang Yang Xue Zhang Ying Li 

机构地区：[1]Institute of Metal Research,Chinese Academy of Sciences,Shenyang,110016,China [2]School of Materials Science and Engineering,University of Science and Technology of China,Shenyang,110016,China

出　　处：《Acta Metallurgica Sinica(English Letters)》2024年第10期1809-1818,共10页金属学报（英文版）

基　　金：financially supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA0410203).

摘　　要：Pyrochemical reprocessing utilizing a molten LiCl-KCl eutectic medium is regarded as the most promising approach for recovering uranium and transuranic elements from spent metallic nuclear fuels.However,the harsh corrosiveness of molten chloride poses a significant challenge to the durability of structural materials.Herein,we report the corrosion behavior of 304 SS,316H SS and Inconel 800H in LiCl-KCl eutectic salt at 550°C for 100 h under an argon atmosphere.Experimental results indicate that all three materials can form a rather continuous Cr_(2)O_(3)-based scale through oxidation reaction at the beginning,but only the scale developed on 800H maintains excellent protection against corrosion throughout the entire exposure period.In contrast,both 304 SS and 316H SS experience considerable active dissolution on the bare substrate under a detached scale.We suggest that the primary reasons for the outstanding resistance of 800H to molten salt corrosion are the high concentration of noble Ni in the system,which lowers the inclination for active dissolution,and the beneficial addition of Al,which accelerates the formation of a less defective Cr_(2)O_(3)-based scale.Our work offers an in-depth understanding on the corrosion performance of high-Cr alloys in molten chloride,insights critical for the selection and subsequent development of structural materials for pyrochemical reprocessing applications.

关 键 词：Corrosion High-chromium alloys Molten salt 

分 类 号：TG146[一般工业技术—材料科学与工程]