金属-有机骨架材料在燃料油催化氧化脱硫中的研究进展  

Research progress of metal-organic framework materials in catalytic oxidation desulfurization of fuel oil

作　　者：闫博文 于鑫宇 毕胜 孙京 丛玉凤[1] Yan Bowen;Yu Xinyu;Bi Sheng;Sun Jing;Cong Yufeng(College of Petrochemical Technology,Liaoning Petrochemical University,Fushun 113001)

机构地区：[1]辽宁石油化工大学石油化工学院,抚顺113001

出　　处：《化工新型材料》2024年第11期32-36,42,共6页New Chemical Materials

基　　金：国家自然科学基金(21702087)。

摘　　要：燃料油催化氧化脱硫技术具有反应条件温和、成本低及芳香族硫化合物易于脱除等优点,制备高效的氧化脱硫催化剂一直是该技术的研究难点。金属-有机骨架(MOFs)材料具有金属中心丰富、比表面积大、孔隙度高及孔隙结构多样等优点,近年来基于MOFs材料的氧化脱硫催化剂的合成及其催化性能研究受到广泛关注。综述了氧化脱硫催化剂的研究现状及负载不同金属的MOFs催化剂在燃料油催化氧化脱硫中的应用进展,并展望了其未来的发展方向。The catalytic oxidation desulfurization technology of fuel oil has the advantages of mild reaction conditions,low cost,and easy removal of aromatic sulfur compounds.The preparation of efficient oxidation desulfurization catalysts has always been a research challenge in this technology.Metal-organic frameworks(MOFs)materials have the advantages of rich metal centers,large specific surface area,high porosity,and diverse pore structures.In recent years,the synthesis and catalytic performance of oxidation desulfurization catalysts based on MOFs materials have received widespread attention.This article reviewed the research status of oxidation desulfurization catalysts and the application progress of MOFs catalysts loaded with different metals in catalytic oxidation desulfurization of fuel oil,and looked forward to their future development directions.

关 键 词：氧化脱硫 金属-有机骨架 催化剂 催化活性 

分 类 号：TE624[石油与天然气工程—油气加工工程]