High thermally stable deep red-emitting Sb^(3+),Ho^(3+)-codoped Cs_(2)NaScCl_(6) double perovskite for plant lighting  

作　　者：Houjiang You Gaoxuanyu Guan Tianchun Lang Mingsheng Cai Peng Su Huichao He Yang Zhong Tao Han 

机构地区：[1]School of Metallurgy and Materials Engineering,Chongqing University of Science and Technology,Chongqing,401331,China [2]School of Material Science and Engineering,Chongqing University of Technology,Chongqing,400054,China [3]Chongqing Key Laboratory of Materials Surface&Interface Science,Chongqing University of Arts and Sciences,Chongqing,402160,China [4]Offshore Oil Engineering Co.,Ltd.,Tianjin,300461,China

出　　处：《Journal of Rare Earths》2024年第11期2043-2050,I0002,共9页稀土学报（英文版）

基　　金：Project supported by the National Natural Science Foundation of China (12174042);the Science and Technology Research Program of Chongqing Municipal Education Commission (KJQN202201338,KJZDM201901301);the Chongqing Talent Plan (CQYC202003058);Fund for Creative Research Group of Micro-Nano Semiconductor & Photonic Materials of Chongqing Municipal Education Commission。

摘　　要：Lead-free halide double perovskite has received widespread attention due to its excellent optical performance.However,the lack of deep red light and poor heat quenching resistance severely limit its application in plant lighting field.In this work,Ho^(3+) was introduced into the thermally stable Cs_(2)NaScCl_(6)host,exhibiting a deep red emission of 660 nm.By constructing an energy transfer channel between Sb^(3+)and Ho^(3+),the photo luminescence quantum yield(PLQY) of Cs_(2)NaScCl_(6):1%Sb^(3+),40%Ho^(3+) rises up to53.8%,that is increased by 17 times,and its emission intensity can still be maintained by 80% at 423 K,exhibiting good heat quenching resistance.The obtained Cs_(2)NaScCl_(6):1%Sb^(3+),40%Ho^(3+) and Cs_(2)NaScCl_(6):1%Sb^(3+) with blue light emission were employed for fabricating a light-emitting diode(LED) device with a340 nm UV chip,and its emission spectrum matches well the absorption spectra of chlorophyll A and chlorophyll B with the high resemblance of 70% and 75%,making it suitable for use as an artificial light source to control the growth process of plants in the field of plant lighting.

关 键 词：Lead-free halide double perovskite Energy transfer Thermally stable Plant lighting Rare earths 

分 类 号：TN312.8[电子电信—物理电子学] TB34[一般工业技术—材料科学与工程]