2020年1月哈尔滨PM_(2.5)重污染形成机制  

Formation Mechanism of Heavy PM_(2.5) Pollution in Harbin in January 2020

作　　者：耿心泽 刘畅[1,2] 刘旭艳 王玉龙 张智清 梁林林 Geng Xinze;Liu Chang;Liu Xuyan;Wang Yulong;Zhang Zhiqing;Liang Linlin(Key Laboratory for Atmospheric Chemistry,Chinese Academy of Meteorological Sciences,Beijing 100081;State Key Laboratory of Severe Weather,Chinese Academy of Meteorological Sciences,Beijing 100081;State Key Laboratory of Urban Water Resource and Environment,School of Environment,Harbin Institute of Technology,Harbin 150090;National Satellite Meteorological Center,Beijing 100081)

机构地区：[1]中国气象科学研究院大气化学重点开放实验室,北京100081 [2]中国气象科学研究院灾害天气国家重点实验室,北京100081 [3]哈尔滨工业大学环境学院城市水资源与水环境国家重点实验室,哈尔滨150090 [4]国家气象卫星中心,北京100081

出　　处：《应用气象学报》2024年第6期737-746,共10页Journal of Applied Meteorological Science

基　　金：国家自然科学基金资助项目(41705109);中国气象科学研究院科技发展基金(2024KJ027);国家重点研发计划(2022YFC3200017-002)。

摘　　要：分析2020年1月哈尔滨重污染事件期间PM_(2.5)的化学组成和影响因素,采用后向轨迹聚类和权重潜在源贡献因子法定量评估区域传输对PM_(2.5)的贡献,讨论该重污染事件的形成机制。结果表明:PM_(2.5)重污染事件主要来源于一次排放,其中生物质燃烧的贡献显著,而极低气温(-18.0℃)和高相对湿度(80.0%)条件可显著促进二次气溶胶的生成。基于气团后向轨迹以及权重潜在源贡献因子研究发现,绥化、大庆、长春和松原等周边城市的区域传输对哈尔滨空气质量的影响也不可忽视。In the context of China’s commitment to improve air quality enhancement,cities within severe cold climate zones,exemplified by Harbin continue to confront the exigent issue of fine particulate matter(PM_(2.5))pollution,notably during winter.Despite nationwide initiatives aimed at mitigating air pollution,Harbin’s unique geographical and climatic conditions,combined with its predominant economic activities,have led to consistently high levels of PM_(2.5) during winter.An episode of severe PM_(2.5) pollution is observed in January 2020,with the monthly average mass concentration of PM_(2.5) peaking at 155.0μg·m^(-3),significantly surpassing national standards.To explore the mechanism of this severe PM_(2.5) pollution episode,an integrated analysis of chemical compositions and influencing factors is conducted during this period.In the meantime,methods of backward trajectory clustering and the weighted potential source contribution function(WPSCF)are employed to investigate source areas and transport pathways of air pollutants.Results indicate that the severe PM_(2.5) pollution in Harbin mainly originates from primary emissions,with biomass burning contributing significantly.During the observation period,the concentration of levoglucosan in PM_(2.5),a common tracer of biomass burning,reaches as high as 1.1μg·m^(-3),which is 3.7 to 5.5 times higher than that in other regions experiencing severe biomass burning pollution during winter.Furthermore,research findings indicate that meteorological conditions play a significant role in exacerbating PM_(2.5) pollution in Harbin.High relative humidity(averaging at 80.0%)combined with extremely low temperatures(averaging at -18.0℃)provided favorable conditions for secondary aerosol formation.Under such low-temperature and high-humidity conditions,the average sulfur oxidation rate reaches as high as 25.6%,and the nitrogen oxidation rate reaches 10.8%.It significantly increases the contribution of secondary aerosols to PM_(2.5) in Harbin.Additionally,this study also rev

关 键 词：严寒气候 生物质燃烧 湿度 PM_(2.5) 区域传输 

分 类 号：X513[环境科学与工程—环境工程]