Mg anode interface engineering in KNO_(3) electrolyte with sodium 5-sulfosalicylate as an additive for enhanced performance of Mg-air batteries  

作　　者：Guanhua Lin Yaqing Zhou Sandrine Zanna Antoine Seyeux Philippe Marcus Jolanta Swiatowska 

机构地区：[1]Chimie ParisTech-CNRS,PSL University,Institut de Recherche de Chimie Paris,11 rue Pierre et Marie Curie,Paris 75005,France [2]International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education,Institute of Microscale Optoelectronics,Shenzhen University,Shenzhen 518060,China

出　　处：《Journal of Magnesium and Alloys》2024年第9期3646-3660,共15页镁合金学报（英文）

基　　金：the China Scholarship Council(CSC)for funding(No.202209350006).

摘　　要：The Mg-air batteries face limitations with pronounced hydrogen evolution and low anodic utilization efficiency from Mg anodes in conventional NaCl electrolytes.The corrosion performance,surface composition,and discharge properties of commercial purity Mg anodes were thoroughly investigated in KNO_(3)electrolytes with and without sodium 5-sulfosalicylate and compared to NaCl electrolyte.The addition of sodium 5-sulfosalicylate to KNO_(3)-based electrolyte results in efficient inhibition of H_(2)evolution,consequently enhancing anodic utilization efficiency to 84%and specific capacity to 1844 mAh/g,compared to NaCl(24%and 534 mAh/g,respectively)under discharge condition of 10 mA/cm^(2)in half cell.Furthermore,the chelating ability of sodium 5-sulfosalicylate can significantly improve the Mg surface dissolution kinetics and discharge product deposition rate at the Mg anode/electrolyte interface,yielding formation of a thinner discharge layer as confirmed by time-of-flight secondary ion mass spectrometry.The discharge voltage is increased to 1.60 V,compared to 1.35 V in KNO_(3)at 0.5 mA/cm^(2)in full cell.However,higher concentration of sodium 5-sulfosalicylate can accelerate Mg anode dissolution,impeding the improvement of anodic utilization efficiency,specific capacity,and energy density.Hence,determining optimal additive concentration and current density is crucial for enhancing the discharge properties of Mg-air batteries and mitigating excessive Mg dissolution in chloride-free electrolytes.

关 键 词：Mg-air batteries Chloride-free electrolytes Discharge properties Structure of surface layer 

分 类 号：TM911.41[电气工程—电力电子与电力传动] O646[理学—物理化学]