Recent progress of radionuclides separation by porous materials  

作　　者：Yinghui Xie Long Yu Long Chen Cheng Chen Li Wang Fenglei Liu Yun Liao Peng Zhang Tao Chen Yihui Yuan Yuexiang Lu Boyang Huang Hui Yang Suhua Wang Shuao Wang Lijian Ma Feng Luo Yunhai Liu Baowei Hu Hongqing Wang Duoqiang Pan Wenkun Zhu Ning Wang Zhe Wang Liang Mao Shengqian Ma Xiangke Wang 

机构地区：[1]Guangdong Provincial Key Laboratory for Green Agricultural Production and Intelligent Equipment,School of Environmental Science and Engineering,Guangdong University of Petrochemical Technology,Maoming 525000,China [2]School of Life Science,Shaoxing University,Shaoxing 312000,China [3]College of Environmental Science and Engineering,North China Electric Power University,Beijing 102206,China [4]State Key Laboratory of Radiation Medicine and Protection,School for Radiological and Interdisciplinary Sciences(RAD-X)and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions,Soochow University,Suzhou 215123,China [5]College of Chemistry,Sichuan University,Chengdu 610064,China [6]School of Chemistry and Materials Science,East China University of Technology,Nanchang 330013,China [7]School of Chemistry and Chemical Engineering,University of South China,Hengyang 421001,China [8]Frontiers Science Center for Rare Isotopes,Lanzhou University,Lanzhou 730000,China [9]State Key Laboratory of Environment-friendly Energy Materials,National Co-innovation Center for Nuclear Waste Disposal and Environmental Safety,Sichuan Civil-military Integration Institute,School of National Defence&Nuclear Science and Technology,Southwest University of Science and Technology,Mianyang 621010,China [10]State Key Laboratory of Marine Resource Utilization in South China Sea,Collaborative Innovation Center of Marine Science and Technology,Hainan University,Haikou 570228,China [11]Institute of Nuclear and New Energy Technology,Tsinghua University,Beijing 100084,China [12]State Key Laboratory of Pollution Control and Resource Reuse,School of the Environment,Nanjing University,Nanjing 210093,China [13]Department of Chemistry,University of North Texas,Denton,TX 76201,USA

出　　处：《Science China Chemistry》2024年第11期3515-3577,共63页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China (22341602, U2067215, 22006036, U2167218, U2341289, 22327807, 22176077);the Beijing Outstanding Young Scientist Program, and the Fundamental Research Funds for the Central Universities (lzujbky-2023-stlt01)。

摘　　要：The separation of radionuclides is critical for the sustainable development of nuclear energy. It is urgent to design and prepare functionalized materials for efficient radionuclides separation. Porous materials are considered excellent candidates for the separation of radionuclides under complex conditions due to their high specific surface areas, tunable pore structures and controllable functionalities. In this review, we summarized the design, preparation and functionalization of porous materials and their application for separation of radionuclides in the past five years, discussed the separation performance and analyzed the structure-activity relationship between various radionuclides and porous materials, and systematically clarified their characterization and mechanism of different type porous materials. We also introduced the detection, irradiation and chemical toxicity of different reflective radionuclides.

关 键 词：porous materials radionuclides DETECTION SEPARATION RADIOTOXICITY interaction mechanism 

分 类 号：TL92[核科学技术—核燃料循环与材料] TB383.4[一般工业技术—材料科学与工程]