Coordination-driven self-assembly of a molecular 818knot and molecular borromean rings  

作　　者：Xiang Gao Dong Liu Hai-Ning Zhang Guo-Xin Jin 

机构地区：[1]Department of Chemistry,Fudan University,Shanghai 200433,China

出　　处：《Science China Chemistry》2024年第11期3652-3656,共5页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China (22031003, 21720102004);Shanghai Science Technology Committee (19DZ2270100)。

摘　　要：We report the facile construction of a molecular 8_(18) knot and a molecular Borromean rings assembly through self-assembly directed by Cp^(*)Rh corner units. Two curved ligands of similar size and shape were used in this study. The slight steric differences between the two ligands induce the formation of distinctly different topologies of the assembled products. The structures were confirmed by single-crystal X-ray analysis and nuclear magnetic resonance spectroscopy.

关 键 词：coordination-driven Cp^(*)Rh 8_(18)knot Borromean rings 

分 类 号：O641.4[理学—物理化学]