HPMo/SiO_(2)/Fe催化剂的合成及催化氧化脱硫研究  

SYNTHESIS OF HPMo/SiO_(2)/Fe CATALYSTS AND CATALYTIC OXIDATIVE DESULFURIZATION

作　　者：孙方力 崔亮[3] 闫锋[1] 王新东 吴田甜 Sun Fangli;Cui Liang;Yan Feng;Wang Xindong;Wu Tiantian(College of Petrochemical Engineering,Liaoning Petrochemical University,Fushun 113001,Liaoning,China;PefroCHina Liaoyang Petrochemicd Branch,Liaoyang 111003,Liaoning,China;Kunlun Lubrication Testing and Evaluation Center of China National Petroleum Corporation,Lanzhou 730060,Gansu,China;PetroChina Fushun Petrochemical Branch,No.3 Petroleum Plant,Fushun 113001,Liaoning,China)

机构地区：[1]辽宁石油化工大学石油化工学院,辽宁抚顺113001 [2]中国石油天然气股份有限公司辽阳石化分公司,辽宁辽阳111003 [3]中国石油天然气股份有限公司昆仑润滑检测评定中心,甘肃兰州730060 [4]中国石油天然气股份有限公司抚顺石化分公司石油三厂,辽宁抚顺113001

出　　处：《精细石油化工》2024年第6期47-52,共6页Speciality Petrochemicals

基　　金：国家科技重大专项课题(2016ZX05010-004-005)。

摘　　要：合成了一种介孔二氧化硅负载磷钼酸(HPMo/SiO_(2))并掺杂金属铁的改性固体催化剂,采用XRD,FT-IR,BET和XPS对其进行表征。将其用于模拟汽油的催化氧化脱硫过程,考察了工艺条件对脱硫性能的影响。结果表明:当Fe负载量为6%、反应时间为60 min、反应温度为60℃、催化剂用量为0.15 g/L、氧硫比为1∶10、萃取时间为15 min时,脱硫率最高可达到92.43%。该催化剂具有良好的循环用性能,回收利用4次后,脱硫率大于70%。A modified solid catalyst of mesoporous silica supported phosphomolybdate(HPMo/SiO_(2))and doped with metallic iron was synthesized and characterized by XRD,FT-IR,BET,and XPS.The prepared catalyst was applied to the catalytic oxidation desulfurization process of simulated gasoline,and the effects of catalyst dosage,reaction time,reaction temperature,Fe loading,extraction time,and other process conditions on the desulfurization performance were investigated.The experimental results showed that when the Fe load was 6%,the reaction time was 60 min,the reaction temperature was 60℃,the catalyst dosage was 0.15 g/L,the oxygen-sulfur ratio was 1∶10,and the extraction time was controlled at 15 min,the highest desulfurization rate could reach 92.43%.The catalyst has good recycling performance,and the desulfurization rate can still reach over 70%after four cycles of recycling,and demonstrating excellent desulfurization performance.

关 键 词：磷钼酸 模拟汽油 催化氧化 脱硫 循环使用 

分 类 号：TQ426.94[化学工程]