Advancements in transition bimetal catalysts for electrochemical 5-hydroxymethylfurfural(HMF) oxidation  

作　　者：Yuwei Li Huiting Huang Mingkun Jiang Wanlong Xi Junyuan Duan Marina Ratova Dan Wu 

机构地区：[1]Key Laboratory of Green Chemical Engineering Process of Ministry of Education,Hubei Key Laboratory of Plasma Chemistry and New Materials,School of Materials Science and Engineering,Wuhan Institute of Technology,Wuhan 430205,Hubei,China [2]Faculty of Science and Engineering,Manchester Metropolitan University,Chester 12 Street,Manchester M15GD,UK

出　　处：《Journal of Energy Chemistry》2024年第11期24-46,共23页能源化学（英文版）

基　　金：Hubei Provincial Natural Science Foundation of China (2023AFB0049);Scientific Research Fund Project of Wuhan Institute of Technology (K202232 and K2023028);Graduate Education Innovation Fund of Wuhan Institute of Technology (CX2023091)。

摘　　要：The electrochemical oxidation of 5-hydroxymethylfurfural(HMF) represents a significant avenue for sustainable chemical synthesis, owing to its potential to generate high-value derivatives from biomass feedstocks. Transition metal catalysts offer a cost-effective alternative to precious metals for catalyzing HMF oxidation, with transition bimetallic catalysts emerging as particularly promising candidates. In this review, we delve into the intricate reaction pathways and electrochemical mechanisms underlying HMF oxidation, emphasizing the pivotal role of transition bimetallic catalysts in enhancing catalytic efficiency. Subsequently, various types of transition bimetallic catalysts are explored, detailing their synthesis methods and structural modulation strategies. By elucidating the mechanisms behind catalyst modification and performance enhancement, this review sets the stage for upcoming advancements in the field, ultimately advancing the electrochemical HMF conversion and facilitating the transition towards sustainable chemical production.

关 键 词：HMF oxidation Transition metal catalysts Bimetallic catalysts Biomass valorization Electrocatalyst synthesis 

分 类 号：TQ251.11[化学工程—有机化工] TQ426