基于灰色关联分析的高性能三元乙丙橡胶多目标配方优化研究  

Research on Multi-Objective Formulation Optimization of High-Performance EPDM Rubber Based on Grey Correlation Analysis

作　　者：詹友基 章蒙蒙 郑天清 许永超 夏永峰 ZHAN You-ji;ZHANG Meng-meng;ZHENG Tian-qing;XU Yong-chao;XIA Yong-feng(School of Mechanical and Automotive Engineering,Fujian University of Technology,Fuzhou 350118,China;Key Laboratory of Intelligent Processing Technology and Equipment in Fujian Province,Fuzhou 350118,China;School of Materials Science and Engineering,Fujian University of Technology,Fuzhou 350118,China;Ningde Sanxing Technology Research Industry and Trade Co.,Ltd.,Ningde 352000,China)

机构地区：[1]福建理工大学机械与汽车工程学院,福建福州350118 [2]福建省智能加工技术及装备重点实验室,福建福州350118 [3]福建理工大学材料科学与工程学院,福建福州350118 [4]宁德三行技研工贸有限公司,福建宁德352000

出　　处：《塑料科技》2024年第10期108-113,共6页Plastics Science and Technology

基　　金：国家自然科学基金(51775113);福建省引导性计划项目(2022H0024);福建省财政厅2023年科技专项资金(GY-Z23274);2021年度宁德市产学研合作项目(宁市科[2021]57)。

摘　　要：三元乙丙橡胶(EPDM)具有良好的耐候性、耐臭氧性、耐水性以及耐化学腐蚀性。为使三元乙丙橡胶的拉伸强度>10 MPa、压变(100℃×22 HR)≤30%、体积变化率<10%,以满足工业上的需要,以三元乙丙橡胶作为研究对象,选取生胶门尼黏度、操作油的黏度、填料的种类及填料的用量为工艺参数进行正交实验,制备不同配方下的硫化橡胶,并对其物理性能进行测量。在此基础上,使用极差分析法得到工艺参数对性能指标的影响主次顺序,随后基于灰色关联理论对实验数据进行多指标简化处理。结果表明:当生胶门尼选用朗盛6950、操作油选用P600、填料使用30份的N774时,三元乙丙橡胶的拉伸强度为13 MPa,压变为30.26%,体积变化率为2.8%。Ethylene propylene diene monomer(EPDM)rubber has good weather resistance,ozone resistance,water resistance,and chemical corrosion resistance.In order to increase the tensile strength of EPDM rubber to>10 MPa and the compressive strain(100℃×22 HR)≤30%,volume change rate<10%to meet industrial needs,the article takes EPDM rubber as the research object,selects raw rubber Mooney viscosity,operating oil viscosity,filler type and filler dosage as process parameters for orthogonal test,prepares vulcanized rubber under different formulations through experimental methods,and measures its physical properties.On this basis,the range analysis method is used to determine the primary and secondary effects of process parameters on performance indicators.Subsequently,the experimental data is simplified using multiple indicators based on grey correlation theory.The results show that when using Langsheng 6950 as raw rubber,P600 as operating oil,and 30 phr of N774 as filler,the tensile strength of EPDM rubber is 13 MPa,the compressive strain is 30.26%,and the volume change rate is 2.8%.

关 键 词：三元乙丙橡胶 灰色关联理论 多目标优化 

分 类 号：TQ333.4[化学工程—橡胶工业]