铜纳米线/高分子导热复合材料的研究进展  

Research progress of Copper Nanowire/Macromolecule Thermal Conductivity Composites

作　　者：刘雅轩 侯佳乐 李新乐 李震奇 马峰岭 石姗姗 姜涛 吴新锋 LIU Ya-xuan;HOU Jia-le;LI Xin-le;LI Zhen-qi;MA Feng-ling;SHI Shan-shan;JIANG Tao;WU Xin-feng(School of Energy and Materials,Shanghai Polytechnic University,Shanghai 201209,China;PetroChina(Shanghai)Advanced Materials Research Institutue Co.,Ltd.,Shanghai 200131,China;Shanghai Research Institute of Materials Co.,Ltd.,Shanghai 200080,China)

机构地区：[1]上海第二工业大学能源与材料学院,上海201209 [2]中石油(上海)新材料研究院有限公司,上海200131 [3]上海材料研究所有限公司,上海200080

出　　处：《塑料科技》2024年第10期154-160,共7页Plastics Science and Technology

基　　金：国家博士后基金(2017M611757)。

摘　　要：通过构建导热网络来增加或拓宽导热通路是制备高导热复合材料的常用途径之一。一维结构的铜纳米线交错或取向处理可以连接成网络结构,大大提高复合材料的散热性能。文章介绍铜纳米线的3种制备方法:模板电沉积法、液相还原法和直接浸渍法。通过不同方法制备出垂直取向且呈现网络结构的铜纳米线热导率较高,作为导热填料可以显著提高材料的导热性能。文章介绍铜纳米线复合材料的6种制备方法:物理共混法、冷冻干燥法、磁场取向法、热压法、溶液浇铸法、真空抽滤法,介绍每种方法的原理,分析各种复合材料成型方式的导热影响因素,概述不同制备方式过程并归纳其导热性能。最后,对填充铜纳米线导热复合材料进行总结和展望。Increasing or broadening the thermal conductivity path by constructing a thermal conductivity network is one of the common ways to prepare high thermal conductivity composites.The interlacing or orientation of copper nanowires with one-dimensional structure can be connected into a network structure,which greatly improves the heat dissipation performance of composites.In this paper,three preparation methods of copper nanowires were introduced:Template electrodeposition method,liquid phase reduction method,and direct impregnation method.The vertically oriented and network structure copper nanowires were prepared by different methods with high thermal conductivity,which can significantly improve the thermal conductivity of the materials as thermal conductive fillers.Six preparation methods of copper nanowire composites were introduced:Physical blending method,freeze-drying method,magnetic field orientation method,hot pressing method,solution casting method,and vacuum filtration method.The principles of each method wereintroduced,the influencing factors of thermal conductivity of various composite molding methods were analyzed,the different preparation methods were summarized,and the thermal conductivity properties of different preparation methods were summarized.Finally,the thermally conductive composites filled with copper nanowires were summarized and prospected.

关 键 词：铜纳米线 热导率 复合材料 制备方法 

分 类 号：TQ317.3[化学工程—高聚物工业]