Three New Hydrogenosuccinate and Succinate Adducts Complexes:Synthesis and Spectroscopic Study  

作　　者：Boucar Diouf Waly Diallo Bocar Traoré Daouda Ndoye Cheikh Abdoul Khadir Diop Mamadou Sidibé 

机构地区：[1]Département de Chimie Laboratoire de Chimie Minérale et Analytique,Facultédes Sciences et Techniques,UniversitéCheikh Anta Diop de Dakar,Dakar 5050,Sénégal

出　　处：《Journal of Environmental Science and Engineering(A)》2024年第6期207-210,共4页环境科学与工程（A）

基　　金：Plasseraud,ICMUB UMR CNRS 6302,University of Burgundy,Faculty of Sciences,Dijon,France.

摘　　要：One new hydrogenosuccinate and two succinate adduct and complex have been synthesized and studied by infrared,UV-Visible and NMR(Nuclear Magnetic Resonance Spectroscopy)^(119)Sn spectroscopies.The suggested structure is discrete,the hydrogenosuccinate behaving as a monodentate ligand or only involved in hydrogen bonding,the environment around the magnesium centre being triangular(compound 3).The succiate anion is a monochelating ligand(compound 1 and 2).In all the suggested structures,when extra hydrogen bonds are considered,supramolecular architectures are obtained(compound 2 and 3).

关 键 词：Discrete structures hydrogen bonds monochelating MONODENTATE triangular or trigonal bipyramidal or tetrahedral environments 

分 类 号：O62[理学—有机化学]