高压储氢容器用高强度可焊接钢板Q690DR配套焊材研发及评价  

Research and development of supporting welding consumables for high-strengthweldable steel plate Q690DR for high-pressure hydrogen storage vessels

作　　者：李双权 梁峰[2] 杨丽 李义民 Li Shuangquan;Liang Feng;Yang Li;Li Yimin(SINOPEC Guangzhou Engineering Co.,Ltd.,Guangzhou,Guangdong 510620;SINOPEC Qingdao Refining&Chemical Co.,Ltd.,Qingdao,Shandong 266500;Digital R&D Center,China Iron&Steel Research Institute Group Co.,Ltd.,Beijing 100081;CISRI Research Institute of Advanced Materials Co.,Ltd.,Shenzhen,Guangdong 518000;Lanzhou LS Heavy Equipment Co.,Ltd.,Lanzhou,Gansu 730314)

机构地区：[1]中石化广州工程有限公司,广东省广州市510620 [2]中国石化青岛炼油化工有限责任公司,山东省青岛市266500 [3]中国钢研科技集团有限公司数字化研发中心,北京市100081 [4]钢研国际新材料创新中心(深圳)有限公司,广东省深圳市518000 [5]兰石重型装备股份有限公司,甘肃省兰州市730314

出　　处：《炼油技术与工程》2024年第11期27-30,共4页Petroleum Refinery Engineering

基　　金：国家重点研发计划资助项目(2022YFB4003000);中国石油化工股份有限公司项目(321126)。

摘　　要：针对可焊接超高强度Q690DR钢板,研制了配套手工焊条CHE807QR,并开展了焊接性能研究。通过斜Y型坡口焊接裂纹试验可知,Q690DR钢板在不预热时冷裂纹敏感性强,预热温度不小于100℃时对冷裂纹不敏感。基于CHE807QR的焊接接头,在150~180℃预热温度下焊态、热处理态的焊接接头,均满足抗拉强度不小于800 MPa、屈服强度不小于690 MPa的要求,-40℃冲击功在110 J左右,其综合力学性能和低温冲击韧性与母材有较好的匹配性。基于低应变速率缺口拉伸测试,测得焊材CHE807QR的焊接接头在10 MPa氢气下与同压力氮气下的相对抗拉强度约为78.08%,在10 MPa氢气环境中,CHE807QR焊接接头的裂纹扩展速率是同等压力氮气环境中的13.5倍左右。CHE807QR焊接接头在10 MPa氮气、10 MPa氢气下的断裂韧度分别约为252.6、113.1 MPa/m^(0.5)。CHE807QR焊材与母材性能高度匹配,满足技术条件要求,可用于高压储氢容器后续试验罐和示范工程项目的建造。For the weldable ultra-high-strength steel plate Q690DR,a matching manual welding rod CHE807QR is developed,and welding performance research is carried out.Through the oblique Y-shaped groove welding crack test,it is evaluated that the Q690DR steel plate has highly cold crack sensitive without preheated,and it is insensitive to cold crack when the preheating temperature is not less than 100℃.Based on CHE807QR,the welded joints and heat treated joints at the preheating temperature of 150-180℃all meet the requirements of tensile strength(R_(m))not less than 800 MPa and yield strength(R_(eL))not less than 690 MPa.The impact energy at-40℃of joint is about 110 J.The mechanical properties and low temperature impact toughness are good matching with the base material.Based on the low strain rate notch tensile test,the relative tensile strength of the welded joint of CHE807QR under 10 MPa hydrogen and the same pressure of nitrogen is about 78.08%.In the 10 MPa hydrogen environment,the crack growth rate of the CHE807QR welded joint is about 13.5 times that of the same pressure nitrogen environment.The fracture toughness of the CHE807QR welded joint under 10 MPa nitrogen is about 252.6 MPa/m^(0.5),and the fracture toughness K IH under 10 MPa hydrogen is about 113.1 MPa/m^(0.5).All in all,the performance of CHE807QR is highly matched with the base material and meets the technical requirements.It can be used for the construction of subsequent test tanks and demonstration projects for high-pressure hydrogen storage vessels.

关 键 词：焊条 Q690DR钢板 焊接接头 冲击功 氢脆敏感性 裂纹扩展速率 断裂韧度 

分 类 号：TK91[动力工程及工程热物理] TG457.11[金属学及工艺—焊接]