异相催化固定二氧化碳合成羰基衍生物的研究进展  

Heterogeneous Catalytic Fixation of Carbon Dioxide for Synthesis of Carbonyl Derivatives

作　　者：张誉元 杨昌杰 唐海涛 潘英明 Zhang Yuyuan;Yang Changjie;Tang Haitao;Pan Yingming(State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources,Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources(Ministry of Education of China),Collaborative Innovation Center for Guangxi Ethnic Medicine,School of Chemistry and Pharmaceutical Sciences,Guangxi Normal University,Guilin,Guangxi 541004)

机构地区：[1]广西师范大学化学与药学学院、省部共建药用资源化学与药物分子工程国家重点实验室、药用资源化学与药物分子工程教育部重点实验室、广西民族药省部共建协同创新中心,广西桂林541004

出　　处：《有机化学》2024年第10期3077-3090,共14页Chinese Journal of Organic Chemistry

基　　金：广西科技基地及人才项目(高层次创新人才及团队培养)(No.Guike AD23026094);国家自然科学基金(No.22161008)资助项目.

摘　　要：异相催化固定CO_(2)的反应作为一种将CO_(2)资源化利用的有效途径,对促进“碳中和”与“碳达峰”具有重要意义,并且该反应的探究对于其他催化体系的建立也具有指导意义.重点介绍了使用异相催化技术在光催化、电催化、热催化、光热催化与光电催化中固定CO_(2)合成系列羰基衍生物反应的最新研究进展,主要介绍了不同异相催化剂催化CO_(2)制备系列羰基衍生物的反应,且采用不同催化方式进行了系统分类,讨论了这些反应的反应机制,为今后设计与实现异相催化固定CO_(2)反应提供了参考.As an effective way to utilize CO_(2) resources,multiphase catalytic carbon fixation is of great significance to promote carbon neutrality and carbon peak.The exploration of this reaction is of guiding significance to the establishment of other catalytic systems.This paper reviews the recent progress in the synthesis of a series of carbon dioxide fixed carbonyl derivatives by heterogeneous catalysis in the fields of photocatalysis,electrocatalysis,thermal catalysis,and photothermal catalysis.The synthesis of carbonyl derivatives by different heterogeneous catalysis CO_(2),including organic carbonates,carbamates and carboxylic acids,is introduced.The reaction mechanism of these reactions is discussed.This provides a reference for the design and realization of the polyphase catalytic fixed CO_(2) reaction.

关 键 词：异相催化 固定二氧化碳 羰基衍生物 

分 类 号：O643.36[理学—物理化学] O622[理学—化学]