单核铁配合物催化氧化环己烷研究进展  

Recent advances in the catalytic oxidation of cyclohexane by mononuclear iron complexes

作　　者：钟良坤 金汉强 崔朝亮 Zhong Liangkun;Jin Hanqiang;Cui Zhaoliang(SINOPEC Nanjing Research Institute of Chemical Industry Co.,Ltd.,Nanjing 210048;State Key Laboratory of Materials-Oriented Chemical Engineering,College of Chemical Engineering,Nanjing Tech University,Nanjing 210009)

机构地区：[1]中石化南京化工研究院有限公司,南京210048 [2]南京工业大学材料化学工程国家重点实验室,南京210009

出　　处：《化工新型材料》2024年第S02期360-364,共5页New Chemical Materials

基　　金：国家重点研发计划(2020YFC0862903)。

摘　　要：金属配合物催化氧化环己烷生成环己醇和环己酮是催化化学领域中一个常见的课题。介绍了不同配合形式的单核铁配合物催化剂在该领域的研究进展,主要包括苯基配合物、杂环配合物、席夫碱型配合物、构象控制型杂环配合物。并简要分析了铁基配合物的结构和性质。此外,对于铁基配合物在催化氧化环己烷方面的未来发展进行了总结和讨论。The catalytic oxidation of cyclohexane to produce cyclohexanol and cyclohexanone by metal complexes is a common topic in the field of catalytic chemistry.This review introduced the research progress of mononuclear iron-based complex catalysts with different coordination forms in this field,including phenyl complexes,heterocyclic complexes,Schiff base complexes,conformation-controlled heterocyclic complexes.The structures and properties of the iron-based complexes were analyzed.In addition,a summary and discussion were conducted on the future development of iron-based complex catalysts in catalytic oxidation of cyclohexane.

关 键 词：单核铁 配合物 催化 氧化 环己烷 

分 类 号：TQ13[化学工程—无机化工]