Electron donor-acceptor complex enabled arylation of dithiocarbamate anions with thianthrenium salts under aqueous micellar conditions  

作　　者：Rong-Nan Yi Wei-Min He 

机构地区：[1]Key Laboratory of Food&Environment&Drug Monitoring and Testing of Universities in Hunan Province,Hunan Police Academy,Changsha 410138,China [2]School of Chemistry and Chemical Engineering,University of South China,Hengyang 421001,China

出　　处：《Chinese Chemical Letters》2024年第11期1-2,共2页中国化学快报（英文版）

摘　　要：Considering the widespread presence of the dithiocarbamate skeleton in pharmaceuticals and bioactive molecules,the development of novel and convenient methods for the synthesis of these useful sulfur-containing compounds is of significant interest.Traditionally,S-aryl dithiocarbamates are constructed through the reaction of amines with thiophenols and thiophosgene[1].Recently,transition-metal-catalyzed Ullmann-type coupling between aryl boronic acids or iodoarenes with tetraalkylthiuram disulfides or sodium dialkyldithiocarbamates has been reported[2].

关 键 词：ALKYL donor SALTS 

分 类 号：O621.255.9[理学—有机化学]