Application of metal-organic frameworks to the anode interface in metal batteries  

作　　者：Ze Liu Xiaochen Zhang Jinlong Luo Yingjian Yu 

机构地区：[1]College of Physics Science and Technology,Kunming University,Kunming 650214,China

出　　处：《Chinese Chemical Letters》2024年第11期182-202,共21页中国化学快报（英文版）

基　　金：financial support from the National Natural Science Foundation of China (No.61904073);Spring City Plan-Special Program for Young Talents (No.K202005007);Yunnan Local Colleges Applied Basic Research Projects (Nos.202101BA070001-138,2018FH001-016);Yunnan Talents Support Plan for Yong Talents (No.XDYC-QNRC-2022-0482);Frontier Research Team of Kunming University 2023,and Yunnan Provincial Education Department (Nos.2022Y732,2022Y739)。

摘　　要：Metal batteries have attracted considerable attention from researchers because of their low reduction voltage and high specific capacity.However,the reduction in the capacity and lifespan of batteries caused by the dendrite growth of metal anode limits the development of metal batteries.Metal-organic frameworks (MOFs) can be used to protect metal anodes owing to their advantages of ideal specific surface area,tunable porosity,and physiochemical stability in electrolytes.Therefore,MOFs have been extensively investigated in metal batteries.The introduction of MOFs to the metal anode interface can greatly improve the performance of batteries.In this review,the synthesis methods of typical MOFs and their derivatives,their protective mechanism on the metal anode,including Li,Na,K,Zn,and Mg,and their effects on the performance of metal batteries were elucidated.This review would help to design and apply MOFs to the anode interface in metal batteries.

关 键 词：Metal-organic frameworks Metal batteries Anode interface Dendrite growth Synthesis methods 

分 类 号：TB34[一般工业技术—材料科学与工程] TM912[电气工程—电力电子与电力传动]