Crown aldoxime ethers:Their synthesis,structure,acid-catalyzed/photo-induced isomerization and adjustable guest binding  

作　　者：Yulin Mao Jingyu Ma Jiecheng Ji Yuliang Wang Wanhua Wu Cheng Yang 

机构地区：[1]Key Laboratory of Green Chemistry&Technology of Ministry of Education,College of Chemistry,Sichuan University,Chengdu 610065,China [2]Laboratory of Precision Cancer Therapeutics,Precision Medicine Research Center,West China Hospital,Sichuan University,Chengdu 610041,China

出　　处：《Chinese Chemical Letters》2024年第11期318-322,共5页中国化学快报（英文版）

基　　金：support of the National Natural Science Foundation of China (Nos.22271201,92056116,22171194,22201194);the Science & Technology Department of Sichuan Province (Nos.2022YFH0095 and 2021ZYD0052);the Fundamental Research Funds for the Central Universities (No.20826041D4117)。

摘　　要：A series of novel crown aldoxime ethers were synthesized,demonstrating notable thermal and hydrolysis stability.The showcased acid-catalyzed and photo-induced cis/trans isomerization,which enables orthogonal control over both guest complexation and the chiroptical effects of these crown aldoxime ethers,manifesting a regulation of complexation through isomerization at binding heteroatoms.

关 键 词：Crown aldoxime ether Cis/trans isomerization PHOTOISOMERIZATION Chiroptical induction Orthogonal control 

分 类 号：O624[理学—有机化学]