光催化苄位C-H键官能团化研究进展  

Advances in Photocatalytic Functionalization of Benzyl C-H Bonds

作　　者：张艳敏 王君 郭国哲[1] 赵乐 ZHANG Yan-min;WANG Jun;GUO Guo-zhe;ZHAO Le(Gansu Longdong Key Laboratory of Efficient Utilization of Oil and Gas Resources,College of Petroleum and Chemical Engineering,Longdong University,Qingyang 745000,China;Licai Gansu Xifeng Pharmaceutical Co.,Ltd.,Qingyang 745700,China)

机构地区：[1]陇东学院石油化工学院甘肃省陇东油气资源高效利用重点实验室,甘肃庆阳745000 [2]丽彩甘肃西峰制药有限公司,甘肃庆阳745700

出　　处：《化学试剂》2024年第12期22-31,共10页Chemical Reagents

基　　金：甘肃省自然科学基金项目(23JRRM0754);陇东学院横向项目(HXZK2413);陇东学院博士基金项目(XYBYZK2224);甘肃省教育科学“十四五”规划2024年度课题资助项目(GS[2024]GHB1516)。

摘　　要：光催化苄位C-H键官能团化在有机合成中的重要性和潜力日益凸显。这一技术在绿色化学与可持续发展的背景下,成为研究热点。利用光催化技术,能够在温和的反应条件下,高效地向苄位引入各种官能团,为复杂有机分子的合成提供了新的途径。该方法不仅简化了合成步骤,还大大提高了产率,为底物结构带来了更多的多样性。对近几年光催化苄位C—H键官能团化反应的研究进行了全面综述,深入探讨了其在合成中的应用。这一领域的发展,不仅推动了有机合成领域的技术进步,也为环境保护和可持续发展做出了积极贡献。The photocatalytic functional group of the benzyl C-H bond has become a research hotspot under the background of green chemistry and sustainable development because of its increasing significance and potential in the field of organic synthesis.By using photocatalysis,various functional groups can be efficiently introduced into benzyl sites under mild reaction conditions,providing a new way for synthesizing complex organic molecules.This method simplifies the synthesis process,increases the yield,and brings more diversity to the structures of substrates.The recent research on photocatalytic functional group reactions of benzyl C-H bonds was reviewed and their applications in synthesis were discussed.This field′s development has not only promoted technological progress in organic synthesis,but also made a positive contribution to environmental protection and sustainable development.

关 键 词：苄位 C-H官能团化 光催化 烃基化 羧基化 酰基化 

分 类 号：O65[理学—分析化学]