Lead-free organic-inorganic hybrid scintillators for X-ray detection  

作　　者：Haixia Cui Wenjuan Zhu Yongjing Deng Tianxiang Jiang Aoxi Yu Huiyu Chen Shujuan Liu Qiang Zhao 

机构地区：[1]State Key Laboratory of Organic Electronics and Information Displays and Jiangsu Key Laboratory for Biosensors,Institute of Advanced Materials(IAM)and Institute of Flexible Electronics(Future Technology),Nanjing University of Posts and Telecommunications(NUPT),Nanjing,Jiangsu,P.R.China [2]College of Electronic and Optical Engineering and College of Flexible Electronics(Future Technology),Jiangsu Province Engineering Research Center for Fabrication and Application of Special Optical Fiber Materials and Devices,Nanjing University of Posts and Telecommunications(NUPT),Nanjing,Jiangsu,P.R.China

出　　处：《Aggregate》2024年第2期1-16,共16页聚集体（英文）

基　　金：National Key R&D Program of China,Grant/Award Number:2023YFE0202500;National Natural Science Foundation of China,Grant/Award Numbers:62375142,62005241。

摘　　要：Scintillators,which can convert high-energy particles(X-rays)into detectable lowenergy ultraviolet-visible-near-infrared photons,are essential components of X-ray detectors and show extensive practical applications in nondestructive detection and medical imaging.Traditionally,inorganic scintillators represented by CsI:Tl have achieved definite progress.However,the harsh preparation conditions,high production cost,and poor mechanical properties impede their potential development in the high-end X-ray imaging field.Organic-inorganic hybrid metal complexes could be excellent alternatives,by virtue of their structural and spectral tunability,good solution processability,and excellent photophysical properties.This review mainly focuses on eco-friendly lead-free metal(Mn^(2+),Cu^(+),Sb^(3+),Sn^(2+),Ge^(2+),Ln^(3+),etc.)complex scintillators.The luminescence mechanisms are introduced and the scintillation performance,such as light yield,limit of detection,imaging resolution,etc.,is highlighted.Moreover,the current challenges and perspectives in this emerging field are described.It is hoped to provide some theoretical guidance for the continuous development of the new scintillator systems.

关 键 词：luminescence mechanisms organic-inorganic hybrid metal complexes scintillation performance SCINTILLATORS X-ray detection and imaging 

分 类 号：O57[理学—粒子物理与原子核物理]