Nonconventional aggregation-induced emission polysiloxanes:Structures,characteristics,and applications  

作　　者：Yan Zhao Lei Xu Yanyun He Zhixuan Feng Weixu Feng Hongxia Yan 

机构地区：[1]Research&Development Institute of Northwestern Polytechnical University in Shenzhen,Shenzhen,China [2]Xi’an Key Laboratory of Hybrid Luminescent Materials and Photonic Device,School of Chemistry and Chemical Engineering,Northwestern Polytechnical University,Xi’an,China

出　　处：《Aggregate》2024年第2期82-98,共17页聚集体（英文）

基　　金：Guangdong Basic and Applied Basic Research Foundation,Grant/Award Number:2020A1515110540;Key Research and Development Program of Shaanxi,Grant/Award Number:2022SF-599;Fundamental Research Funds for the Central Universities,Grant/Award Number:D5000230114;National Natural Science Foundation of China,Grant/Award Number:22175143。

摘　　要：Nonconventional luminescent materials have been rising stars in organic luminophores due to their intrinsic characteristics,including water-solubility,biocompatibility,and environmental friendliness and have shown potential applications in diverse fields.As an indispensable branch of nonconventional luminescent materials,polysiloxanes,which consist of electron-rich auxochromic groups,have exhibited outstanding photophysical properties due to the unique silicon atoms.The flexible Si-O bonds benefit the aggregation,and the empty 3d orbitals of Si atoms can generate coordination bonds including N→Si and O→Si,altering the electron delocalization of the material and improving the luminescent purity.Herein,we review the recent progress in luminescent polysiloxanes with different topologies and discuss the challenges and perspectives.With an emphasis on the driving force for the aggregation and the mechanism of tuned emissions,the role of Si atoms played in the nonconventional luminophores is highlighted.This review may provide new insights into the design of nonconventional luminescent materials and expand their further applications in sensing,biomedicine,lighting devices,etc.

关 键 词：aggregation-induced emission molecular structure nonconventional luminescent polymer photoluminescence property POLYSILOXANE 

分 类 号：O48[理学—固体物理]