Molecular catalysts for electrocatalytic ammonia oxidation  

作　　者：Jun Li Feiyang Zhang Huatian Xiong Yuanyuan Cai Biaobiao Zhang 

机构地区：[1]Center of Artificial Photosynthesis for Solar Fuels and Department of Chemistry,School of Science and Research Center for Industries of the Future,Westlake University,Hangzhou 310030,China [2]Institute of Natural Sciences,Westlake Institute for Advanced Study,Hangzhou 310024,China [3]Division of Solar Energy Conversion and Catalysis at Westlake University,Zhejiang Baima Lake Laboratory Co.,Ltd.,Hangzhou 310000,China

出　　处：《Science China Chemistry》2024年第12期3976-3993,共18页中国科学（化学英文版）

基　　金：supported by the National Key R&D Program of China(2022YFC3401802);the National Natural Science Foundation of China(22279105);the Zhejiang Provincial Natural Science Foundation(XHD24B0201);the Starting-up Package from Westlake University;the Kunpeng Research Fund from Zhejiang Province;Research Center for Industries of the Future;Zhejiang Baima Lake Laboratory。

摘　　要：Electrocatalytic ammonia oxidation reaction(eAOR)is of significance to ammonia fuel economy and the production of valuable N-containing products,such as nitrite,nitrate and hydrazine.The study of well-defined molecular catalysts offers rich insights in terms of the detailed mechanism of ammonia oxidation.This review analyzes the thermodynamics of ammonia oxidation reactions and summarizes the current progress in molecular electrocatalysts in this booming field.We emphasized the factors that influence the selectivity of products and further discussed the challenges in designing efficient catalysts.

关 键 词：ELECTROCATALYTIC ammonia oxidation reaction HYDRAZINE NITRATE molecular catalyst 

分 类 号：O643.36[理学—物理化学]