Catalytic conversion of bioethanol to value-added chemicals and fuels:A review  

作　　者：Huan Xiang Ruojia Xin Natthawan Prasongthum Paweesuda Natewong Tawan Sooknoi Jiawei Wang Prasert Reubroycharoen Xiaolei Fan 

机构地区：[1]Department of Chemical Engineering and Analytical Science,School of Engineering,The University of Manchester,Manchester M139PL,United Kingdom [2]Department of Chemical Engineering and Applied Chemistry,Aston University,Birmingham,B47ET,United Kingdom [3]Expert Centre of Innovative Clean Energy and Environment,Thailand Institute of Scientific and Technological Research(TISTR),35 Mu 3,Khlong Ha,Khlong Luang,Pathum Thani 12120,Thailand [4]Clean Energy Technologies Research Institute(CETRI),Faculty of Engineering&Applied Science,University of Regina,Regina,Saskatchewan,S4S0A2,Canada [5]Department of Chemistry,Faculty of Science,King Mongkut’s Institute of Technology Ladkrabang,Bangkok 10520,Thailand [6]Center of Excellence in Catalysis for Bioenergy and Renewable Chemicals(CBRC),Faculty of Science,Chulalongkorn University,Bangkok 10330,Thailand

出　　处：《Resources Chemicals and Materials》2022年第1期47-68,共22页资源化工与材料（英文）

基　　金：funding from the European Union’s Hori-zon 2020 research and innovation programme under grant agree-ment No 872102;H.X.thanks The University of Manchester Presi-dent’s Doctoral Scholar Award and the China Scholarship Council(file no.201606150068)for supporting her PhD research.

摘　　要：Bioethanol produced via valorisation of renewable biomass is of great interest to many industries.The increased availability and decreased cost of bioethanol make it a promising platform molecule to produce a wide range of value-added chemicals and fuels via the catalytic conversions.This paper provides a comprehensive review of catalytic conversions of bioethanol to a variety of chemicals/fuels such as hydrogen,C_(2)-C_(4)olefins,gasoline and small oxygenates.Specifically,the focus was placed on the relationship between the catalyst property(such as pore structure,acidity,active metal sites,and catalyst supports)and the catalytic performance(including catalyst activity and stability),as well as the reaction mechanisms involved.Future research avenues on the catalyst design for improving catalytic valorisation of bioethanol are also discussed.

关 键 词：BIOETHANOL CATALYSIS Hydrogen C_(2)-C_(4)olefins GASOLINE OXYGENATES 

分 类 号：O64[理学—物理化学]