Metal-Decorated Porous Organic Polymers:Bridged the Gap between Organic and Inorganic Scaffolds  

作　　者：Zhu Gao Yufei Liu Shaofei Wu Juntao Tang Kuanyu Yuan Chunyue Pan Guipeng Yu 

机构地区：[1]College of Chemistry and Chemical Engineering,Central South University,Changsha,Hunan 410083,China [2]School of Chemistry,Chemical Engineering and Materials,Jining University,Qufu,Shandong 273100,China [3]Department of Chemistry,National University of Singapore,3 Science Drive 3,117543,Singapore

出　　处：《Chinese Journal of Chemistry》2024年第22期2902-2934,共33页中国化学（英文版）

基　　金：supported by the National Natural Science Foundation of China(Nos.52173212,and 52103275);Hunan Provincial Natural Science Foundation for Distinguished Young Scientists(2022J10080);the Key Science and Technology Project of Changsha(KH2301015).

摘　　要：Advanced functionalization-decorated porous organic polymers(POPs)are emerging as a prominent research focus,spanning from their construction to applications in gas storage and separation,catalysis,energy storage,electrochemistry,and other areas.Furthermore,the inherent organic nature,tailored pore structures,and adjustable chemical components of POPs offer a versatile platform for the incorporation of various metal active sites.Meticulously designed molecular building blocks can serve as organic ligands uniformly distributed throughout POPs,leading to the effective isolation of inorganic metal active sites at the molecular level.In this manner,POPs containing active metal centers bridge the gap between organic and inorganic scaffolds.This review aims to provide an overview of recent research progress on metal-decorated POPs,focusing on strategies for incorporating metal active sites into POPs and their applications in adsorption,separation,catalysis,and photoelectrochemistry.Finally,current challenges and future prospects are discussed for further research.

关 键 词：Porous polymers Metal functionalization Adsorption CATALYSIS Active sites Functional polymers 

分 类 号：O64[理学—物理化学]