Rhodium-Catalyzed C(sp^(3))–H Arylation of 8-Methylquinolines with Arylsilanes  

作　　者：Lin Li Haidong Liu Yupeng Qian Guohong Shen Yun Shi Jiajie Du Haiqing Luo 

机构地区：[1]Department of Chemistry&Chemical Engineering,Gannan Normal Univeristy,Ganzhou,Jiangxi,341000 China

出　　处：《Chinese Journal of Chemistry》2024年第21期2627-2632,共6页中国化学（英文版）

基　　金：supported by the National Natural Science Foundation of China(22271062);Doctoral Scientific Research Foundation of Gannan Normal University(BSJJ202303).

摘　　要：We herein describe a Cp^(*)Rh^(Ⅲ)-catalyzed C(sp^(3))–H mono-arylation of 8-methylquinolines with benign arylsilanes.The use of 1-adamantane carboxylic acid can benefit the efficiency in this transformation,and AgF was both activator and reoxidant.Control experiments indicated inability of C—H cleavage in determining the rate of the reaction.

关 键 词：C(sp^(3))-H arylation C-H activation ARYLSILANES CROSS-COUPLING Nitrogen heterocycles 

分 类 号：O62[理学—有机化学]