CO_(2)分离反应一体化复合膜材料研究进展  

Research progress in CO_(2) separation and reaction integratedcomposite membrane material

作　　者：邱月 王艳磊 王榕榕 李华[2] 路建美[2] 何宏艳[1] Yue Qiu;Yanlei Wang;Rongrong Wang;Hua Li;Jianmei Lu;Hongyan He(Beijing Key Laboratory of Ionic Liquids Clean Process,State Key Laboratory of Mesoscience and Engineering,CAS Key Laboratory of Green Process and Engineering,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100190,China;College of Chemistry,Chemical Engineering and Materials Science,Collaborative Innovation Center of Suzhou Nano Science and Technology,Soochow University,Suzhou 215123,China)

机构地区：[1]中国科学院过程工程研究所,离子液体清洁过程北京市重点实验室,北京100190 [2]苏州大学材料与化学化工学部,苏州纳米科技协同创新中心,苏州215123

出　　处：《中国科学：化学》2024年第11期2122-2131,共10页SCIENTIA SINICA Chimica

基　　金：国家重点研发计划(编号:2021YFB3802600);国家自然科学基金(编号:22178344)资助。

摘　　要：近年来,化石燃料燃烧和温室气体排放引起的全球变暖问题日益受到关注,CO_(2)的捕集与转化成为全球焦点.相比传统的CO_(2)捕集分离技术,膜技术因其在分离效率和能耗方面的优势而备受瞩目.特别是,将膜技术与催化反应相结合,制备分离反应一体化复合膜材料,不仅能有效分离CO_(2),还能原位将其转化为有价值的化学品,从而实现CO_(2)高效资源化利用的目标.本综述首先介绍了CO_(2)分离膜的分离机理和膜材料;然后结合膜反应器,介绍了CO_(2)膜催化的最新研究成果和发展趋势;最后基于离子液体体系,讨论了CO_(2)分离反应一体化复合膜材料研制的挑战和展望,以期为相关领域的研究人员提供参考,推动CO_(2)减排和资源化利用技术的发展.In recent years,global warming caused by fossil fuel combustion and greenhouse gas emissions has become a growing concern,making the issue of CO_(2) capture and conversion the focus of global attention.Compared to conventional CO_(2) capture and separation technologies,membrane technology is highly attractive for its advantages in terms of separation efficiency and energy consumption.In particular,by combining membrane technology with catalytic reaction to prepare separation and reaction integrated composite membrane materials,CO_(2) can be effectively separated and converted into valuable chemicals in situ,thus realizing the goal of efficient resource utilization of CO_(2).This review first introduces the CO_(2) separation membrane separation mechanism and membrane materials.Then,the latest research results and development trend of CO_(2) membrane catalysis are introduced in conjunction with the membrane reactor.Finally,based on the ionic liquid system,the challenges and prospects for the development of integrated composite membrane materials for CO_(2) separation and reaction are discussed,with a view to providing references for researchers in related fields and promoting the development of CO_(2) emission reduction and resource utilization technologies.

关 键 词：分离膜材料 CO_(2)催化 膜反应器 分离反应耦合一体化 

分 类 号：X701[环境科学与工程—环境工程] TQ051.893[化学工程]