过氧化氢在水处理中的应用与研究进展  

Application and research progress of hydrogen peroxide in water treatment

作　　者：周沄梵 阮秀秀[1] 黄驰[2] 佘远斌[3] ZHOU Yunfan;RUAN Xiuxiu;HUANG Chi;SHE Yuanbin(School of Environmental and Chemical Engineering,Shanghai University,Shanghai 200444,China;College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072,Hubei,China;College of Chemical Engineering,Zhejiang University of Technology,Hangzhou 310014,Zhejiang,China)

机构地区：[1]上海大学环境与化学工程学院,上海200444 [2]武汉大学化学与分子科学学院,湖北武汉430072 [3]浙江工业大学化学工程学院,浙江杭州310014

出　　处：《精细化工》2024年第12期2590-2602,共13页Fine Chemicals

摘　　要：过氧化物广泛应用于水处理领域,对水体中的重金属离子、有害细菌、难降解有机物有良好的去除效果,其研发与普及成为环保领域高度关注的课题。该文综述了在高级氧化技术中过氧化氢不同活化方式在水处理过程中的作用机制及其应用研究进展。主要从活化过氧化氢、减少过氧化氢消耗2个方面重点探讨了近年来不断发展的催化剂活化、外加能量活化、与其他氧化剂联用活化过氧化氢及过氧化氢光催化与电催化的原位生成在水处理中的研究和应用进展。针对过氧化物的新型活化方式有较大的研究潜力,对拓展和加速推进新型过氧化物在水处理领域的应用与研究及过氧化物缓释材料在减少过氧化物对体系中催化剂与稳定性的影响进行了展望。Peroxides are widely used in the field of water treatment,and have good removal effects on heavy metal ions,harmful bacteria and difficult to degrade organic matter in water bodies.Their research and development and popularization have become highly concerned topics in the field of environmental protection.The mechanism and application research progress of different activation modes of hydrogen peroxide in advanced oxidation in the water treatment process were reviewed.The research and application progress of catalyst activation,external energy activation,activation of hydrogen peroxide in combination with other peroxides,photocatalytic and electrocatalytic in situ generation of hydrogen peroxide in water treatment were discussed from the two aspects of activation and reduction of hydrogen peroxide consumption.In view of the great research potential of new activation modes of peroxides,it was expected to expand and accelerate the application and research of new peroxides in the field of water treatment and to reduce the influence of peroxides on catalysts and stability in the system.

关 键 词：过氧化物 过氧化氢 高级氧化 水处理 活化机制 

分 类 号：TQ123.6[化学工程—无机化工] TU992.3[建筑科学—市政工程]