离子液体促进CO_(2)环加成反应的理论研究进展  

Theoretical Research Progress of Ionic Liquids Promoting CO_(2) Cycloaddition Reaction

作　　者：陆俊凤 孙怀宇[1] LU Junfeng;SUN huaiyu(School of Chemical Engineering,Shenyang University of Chemical Technology,Shenyang Liaoning 110142,China)

机构地区：[1]沈阳化工大学,辽宁沈阳110142

出　　处：《辽宁化工》2024年第11期1734-1737,1745,共5页Liaoning Chemical Industry

摘　　要：离子液体(ILs)具有物理化学性质稳定、不易挥发、结构功能可调等优点,广泛应用于CO_(2)的环加成反应。作为一种新型研发手段,理论计算能够从一定角度解释实验现象,揭示反应机理,为新型催化剂设计提供理论指导和方向。从均相和非均相ILs体系的角度,综述了近年来ILs促进CO_(2)环加成反应的理论研究进展,并对未来进行了展望。Ionic liquids(ILs),with stable physical and chemical properties,low volatility,and adjustable structure and function,have been widely used in the cycloaddition reaction of CO_(2).As a novel research tool,theoretical calculations help to explain experimental phenomena and reveal reaction mechanisms from a certain perspective,providing theoretical guidance and direction for new catalyst designs.In this paper,the progress of theoretical studies on the promotion of CO_(2) cycloaddition reactions by ILs in recent years was reviewed from the perspectives of both homogeneous and heterogeneous ILs systems,and an outlook on the future was proposed.

关 键 词：离子液体 CO_(2) 环加成 理论计算 

分 类 号：TQ235[化学工程—有机化工]